Tetra­ammineplatinum(II) dichloride ammonia tetra­solvate

The title compound, [Pt(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt PtCl(2). The platinum cation is coordinated by four ammonia mol­ecules, forming a square-planar complex. The chloride anions are surrounded by nine ammonia mol­ecules, either bound within the platinum co...

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Detalles Bibliográficos
Autores principales: Grassl, Tobias, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120569/
https://www.ncbi.nlm.nih.gov/pubmed/25161504
http://dx.doi.org/10.1107/S1600536814012343
Descripción
Sumario:The title compound, [Pt(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt PtCl(2). The platinum cation is coordinated by four ammonia mol­ecules, forming a square-planar complex. The chloride anions are surrounded by nine ammonia mol­ecules, either bound within the platinum complex or solvent mol­ecules. The solvent ammonia mol­ecules are packed in such a way that an extended network of N—H⋯N and N—H⋯Cl hydrogen bonds is formed. The structure is isotypic with [Pd(NH(3))(4)]Cl(2)·4NH(3) [Grassl & Korber (2014). Acta Cryst. E70, i32].

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