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(E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one
In the title molecule, C(22)H(18)O, the o-tolyl ring is connected through a conjugated double bond. The molecule adopts an E conformation and the C—C=C—C torsion angle is 178.77 (13)°. The overall conformation may be described by the values of dihedral angles between the different planes. The term...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120573/ https://www.ncbi.nlm.nih.gov/pubmed/25161590 http://dx.doi.org/10.1107/S1600536814014317 |
| _version_ | 1782329110677159936 |
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| author | Shanthi, D. Vidhya Sagar, T. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. |
| author_facet | Shanthi, D. Vidhya Sagar, T. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. |
| author_sort | Shanthi, D. |
| collection | PubMed |
| description | In the title molecule, C(22)H(18)O, the o-tolyl ring is connected through a conjugated double bond. The molecule adopts an E conformation and the C—C=C—C torsion angle is 178.77 (13)°. The overall conformation may be described by the values of dihedral angles between the different planes. The terminal rings are twisted by an angle of 54.75 (8)°, while the biphenyl part is not planar, the dihedral angle between the planes of the rings being 40.65 (8)°. The dihedral angle between the benzene rings is 14.10 (7)°. There are three weak C—H⋯π interactions found in the crystal structure. No classic hydrogen bonds are observed. |
| format | Online Article Text |
| id | pubmed-4120573 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41205732014-08-26 (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one Shanthi, D. Vidhya Sagar, T. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(22)H(18)O, the o-tolyl ring is connected through a conjugated double bond. The molecule adopts an E conformation and the C—C=C—C torsion angle is 178.77 (13)°. The overall conformation may be described by the values of dihedral angles between the different planes. The terminal rings are twisted by an angle of 54.75 (8)°, while the biphenyl part is not planar, the dihedral angle between the planes of the rings being 40.65 (8)°. The dihedral angle between the benzene rings is 14.10 (7)°. There are three weak C—H⋯π interactions found in the crystal structure. No classic hydrogen bonds are observed. International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120573/ /pubmed/25161590 http://dx.doi.org/10.1107/S1600536814014317 Text en © Shanthi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Shanthi, D. Vidhya Sagar, T. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| title | (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| title_full | (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| title_fullStr | (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| title_full_unstemmed | (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| title_short | (E)-1-([1,1′-Biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| title_sort | (e)-1-([1,1′-biphenyl]-4-yl)-3-(2-methylphenyl)prop-2-en-1-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120573/ https://www.ncbi.nlm.nih.gov/pubmed/25161590 http://dx.doi.org/10.1107/S1600536814014317 |
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