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(E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate

In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide mol­ecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water mol­ecule acts as an acceptor, forming...

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Detalles Bibliográficos
Autores principales: Novina, J. Josephine, Vasuki, G., Suresh, M., Padusha, M. Syed Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120580/
https://www.ncbi.nlm.nih.gov/pubmed/25161576
http://dx.doi.org/10.1107/S1600536814013798
Descripción
Sumario:In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide mol­ecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water mol­ecule acts as an acceptor, forming an N—H⋯O hydrogen bond supported by two C—H⋯O contacts. It also acts as a donor, forming bifurcated O—H⋯(O,O) and O—H⋯N hydrogen bonds that combine with the former contacts to form zigzag chains of mol­ecules along the c-axis direction. An additional O—H⋯O donor contact completes a set of six hydrogen bonds to and from the water mol­ecule and connects it to a third nicotinohydrazide mol­ecule. This latter contact combines with weaker C—H⋯O hydrogen bonds supported by a C—H⋯π contact to stack mol­ecules along b in a three-dimensional network.