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(E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate

In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide mol­ecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water mol­ecule acts as an acceptor, forming...

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Autores principales: Novina, J. Josephine, Vasuki, G., Suresh, M., Padusha, M. Syed Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120580/
https://www.ncbi.nlm.nih.gov/pubmed/25161576
http://dx.doi.org/10.1107/S1600536814013798
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author Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
author_facet Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
author_sort Novina, J. Josephine
collection PubMed
description In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide mol­ecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water mol­ecule acts as an acceptor, forming an N—H⋯O hydrogen bond supported by two C—H⋯O contacts. It also acts as a donor, forming bifurcated O—H⋯(O,O) and O—H⋯N hydrogen bonds that combine with the former contacts to form zigzag chains of mol­ecules along the c-axis direction. An additional O—H⋯O donor contact completes a set of six hydrogen bonds to and from the water mol­ecule and connects it to a third nicotinohydrazide mol­ecule. This latter contact combines with weaker C—H⋯O hydrogen bonds supported by a C—H⋯π contact to stack mol­ecules along b in a three-dimensional network.
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spelling pubmed-41205802014-08-26 (E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide mol­ecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water mol­ecule acts as an acceptor, forming an N—H⋯O hydrogen bond supported by two C—H⋯O contacts. It also acts as a donor, forming bifurcated O—H⋯(O,O) and O—H⋯N hydrogen bonds that combine with the former contacts to form zigzag chains of mol­ecules along the c-axis direction. An additional O—H⋯O donor contact completes a set of six hydrogen bonds to and from the water mol­ecule and connects it to a third nicotinohydrazide mol­ecule. This latter contact combines with weaker C—H⋯O hydrogen bonds supported by a C—H⋯π contact to stack mol­ecules along b in a three-dimensional network. International Union of Crystallography 2014-06-18 /pmc/articles/PMC4120580/ /pubmed/25161576 http://dx.doi.org/10.1107/S1600536814013798 Text en © Novina et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
(E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
title (E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
title_full (E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
title_fullStr (E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
title_full_unstemmed (E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
title_short (E)-N′-(3,4-Di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
title_sort (e)-n′-(3,4-di­meth­oxy­benzyl­idene)nicotinohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120580/
https://www.ncbi.nlm.nih.gov/pubmed/25161576
http://dx.doi.org/10.1107/S1600536814013798
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AT sureshm en34dimethoxybenzylidenenicotinohydrazidemonohydrate
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