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(E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate
In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide molecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water molecule acts as an acceptor, forming...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120580/ https://www.ncbi.nlm.nih.gov/pubmed/25161576 http://dx.doi.org/10.1107/S1600536814013798 |
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author | Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali |
author_facet | Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali |
author_sort | Novina, J. Josephine |
collection | PubMed |
description | In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide molecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water molecule acts as an acceptor, forming an N—H⋯O hydrogen bond supported by two C—H⋯O contacts. It also acts as a donor, forming bifurcated O—H⋯(O,O) and O—H⋯N hydrogen bonds that combine with the former contacts to form zigzag chains of molecules along the c-axis direction. An additional O—H⋯O donor contact completes a set of six hydrogen bonds to and from the water molecule and connects it to a third nicotinohydrazide molecule. This latter contact combines with weaker C—H⋯O hydrogen bonds supported by a C—H⋯π contact to stack molecules along b in a three-dimensional network. |
format | Online Article Text |
id | pubmed-4120580 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41205802014-08-26 (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated compound, C(15)H(15)N(3)O(3)·H(2)O, the nicotinohydrazide molecule adopts a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene and pyridine rings is 5.10 (14)°. In the crystal, the solvent water molecule acts as an acceptor, forming an N—H⋯O hydrogen bond supported by two C—H⋯O contacts. It also acts as a donor, forming bifurcated O—H⋯(O,O) and O—H⋯N hydrogen bonds that combine with the former contacts to form zigzag chains of molecules along the c-axis direction. An additional O—H⋯O donor contact completes a set of six hydrogen bonds to and from the water molecule and connects it to a third nicotinohydrazide molecule. This latter contact combines with weaker C—H⋯O hydrogen bonds supported by a C—H⋯π contact to stack molecules along b in a three-dimensional network. International Union of Crystallography 2014-06-18 /pmc/articles/PMC4120580/ /pubmed/25161576 http://dx.doi.org/10.1107/S1600536814013798 Text en © Novina et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate |
title | (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate |
title_full | (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate |
title_fullStr | (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate |
title_full_unstemmed | (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate |
title_short | (E)-N′-(3,4-Dimethoxybenzylidene)nicotinohydrazide monohydrate |
title_sort | (e)-n′-(3,4-dimethoxybenzylidene)nicotinohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120580/ https://www.ncbi.nlm.nih.gov/pubmed/25161576 http://dx.doi.org/10.1107/S1600536814013798 |
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