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4-[(4-Bromophenyl)amino]-2-methylidene-4-oxobutanoic acid
In the title compound, C(11)H(10)BrNO(3), two independent molecules (A and B) crystallize in the asymmetric unit. The dihedral angles between the mean planes of the 4-bromophenyl ring and amide group are 24.8 (7) in molecule A and 77.1 (6)° in molecule B. The mean plane of the methylidene group...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120590/ https://www.ncbi.nlm.nih.gov/pubmed/25161566 http://dx.doi.org/10.1107/S1600536814012872 |
Sumario: | In the title compound, C(11)H(10)BrNO(3), two independent molecules (A and B) crystallize in the asymmetric unit. The dihedral angles between the mean planes of the 4-bromophenyl ring and amide group are 24.8 (7) in molecule A and 77.1 (6)° in molecule B. The mean plane of the methylidene group is further inclined by 75.6 (4) in molecule A and 72.5 (6)° in molecule B from that of the amide group. In the crystal, N—H⋯O hydrogen bonds formed by amide groups and O—H⋯O hydrogen bonds formed by carboxylic acid groups are observed and supported additionally by weak C—H⋯O interactions between the methylidene and amide groups. Together, these link the molecules into chains of dimers along [110] and form R (2) (2)(8) graph-set motifs. |
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