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4-[(4-Acetyl­phen­yl)amino]-2-methyl­idene-4-oxo­butanoic acid

In the title compound, C(13)H(13)NO(4), the N—C(=O) bond length of 1.354 (2) Å is indicative of amide-type resonance. The dihedral angle between the mean planes of the benzene ring and oxo­amine group is 36.4 (3)°, while the mean plane of the 2-methyl­idene group is inclined by 84.2 (01)° from that...

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Detalles Bibliográficos
Autores principales: Narayana, B., Nayak, Prakash S., Sarojini, Balladka K., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120591/
https://www.ncbi.nlm.nih.gov/pubmed/25161547
http://dx.doi.org/10.1107/S1600536814012562
Descripción
Sumario:In the title compound, C(13)H(13)NO(4), the N—C(=O) bond length of 1.354 (2) Å is indicative of amide-type resonance. The dihedral angle between the mean planes of the benzene ring and oxo­amine group is 36.4 (3)°, while the mean plane of the 2-methyl­idene group is inclined by 84.2 (01)° from that of the oxo­amine group. In the crystal, classical O—H⋯O hydrogen bonds formed by the carb­oxy­lic acid groups and weak N—H⋯O weak inter­actions formed by the amide groups and supported by weak C—H⋯O inter­actions between the 2-methyl­idene, phenyl and acetyl groups with the carb­oxy­lic acid, oxo­amine and acetyl O atoms, together link the mol­ecules into dimeric chains along [010]. The O—H⋯O hydrogen bonds form R (2) (2)(8) graph-set motifs.