2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile

In the crystal structure of the title compound, C(22)H(13)Br(2)N(3), the two bromo­phenyl rings are rotated out of the plane of the central benzyl­idene ring by 68.7 (1) and 69.3 (1)°. Both cyano substituents are located nearly in the plane of the benzylidene ring, with the mean plane of the methylm...

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Detalles Bibliográficos
Autores principales: Zhang, Yu-Jian, Ni, Sheng-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120592/
https://www.ncbi.nlm.nih.gov/pubmed/25161579
http://dx.doi.org/10.1107/S1600536814013816
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author Zhang, Yu-Jian
Ni, Sheng-Liang
author_facet Zhang, Yu-Jian
Ni, Sheng-Liang
author_sort Zhang, Yu-Jian
collection PubMed
description In the crystal structure of the title compound, C(22)H(13)Br(2)N(3), the two bromo­phenyl rings are rotated out of the plane of the central benzyl­idene ring by 68.7 (1) and 69.3 (1)°. Both cyano substituents are located nearly in the plane of the benzylidene ring, with the mean plane of the methylmalononitrile group being inclined to this ring by 5.8 (1)°. In the crystal, the mol­ecules are linked by weak C—H⋯N hydrogen bonds into layers parallel to the bc plane.
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spelling pubmed-41205922014-08-26 2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile Zhang, Yu-Jian Ni, Sheng-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(22)H(13)Br(2)N(3), the two bromo­phenyl rings are rotated out of the plane of the central benzyl­idene ring by 68.7 (1) and 69.3 (1)°. Both cyano substituents are located nearly in the plane of the benzylidene ring, with the mean plane of the methylmalononitrile group being inclined to this ring by 5.8 (1)°. In the crystal, the mol­ecules are linked by weak C—H⋯N hydrogen bonds into layers parallel to the bc plane. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120592/ /pubmed/25161579 http://dx.doi.org/10.1107/S1600536814013816 Text en © Zhang and Ni 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Yu-Jian
Ni, Sheng-Liang
2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
title 2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
title_full 2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
title_fullStr 2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
title_full_unstemmed 2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
title_short 2-{4-[Bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
title_sort 2-{4-[bis(4-bromo­phen­yl)amino]­benzyl­idene}malono­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120592/
https://www.ncbi.nlm.nih.gov/pubmed/25161579
http://dx.doi.org/10.1107/S1600536814013816
work_keys_str_mv AT zhangyujian 24bis4bromophenylaminobenzylidenemalononitrile
AT nishengliang 24bis4bromophenylaminobenzylidenemalononitrile

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