5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one

In the title compound, C(30)H(25)N(3)O(5), the central five-membered heterocyclic ring adopts an envelope conformation, with the N atom as the flap. The dihedral angles between this central ring and the pendant indane ring system, the trione and benzene rings are 87.49 (5), 82.95 (10) and 72.42 (10)...

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Autores principales: Subramanyahegde, Amar, Hosamani, Shivaraj, Yellappa, Vijayakumar, Giriyapura R., Palakshamurthy, Bandrehalli Siddagangaiah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120593/
https://www.ncbi.nlm.nih.gov/pubmed/25161552
http://dx.doi.org/10.1107/S1600536814013117
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author Subramanyahegde,
Amar, Hosamani
Shivaraj, Yellappa
Vijayakumar, Giriyapura R.
Palakshamurthy, Bandrehalli Siddagangaiah
author_facet Subramanyahegde,
Amar, Hosamani
Shivaraj, Yellappa
Vijayakumar, Giriyapura R.
Palakshamurthy, Bandrehalli Siddagangaiah
author_sort Subramanyahegde,
collection PubMed
description In the title compound, C(30)H(25)N(3)O(5), the central five-membered heterocyclic ring adopts an envelope conformation, with the N atom as the flap. The dihedral angles between this central ring and the pendant indane ring system, the trione and benzene rings are 87.49 (5), 82.95 (10) and 72.42 (10)°, respectively. The dihedral angle between the rings of the biphenyl group is 45.99 (13)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds into [101] C(12) chains.
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spelling pubmed-41205932014-08-26 5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one Subramanyahegde, Amar, Hosamani Shivaraj, Yellappa Vijayakumar, Giriyapura R. Palakshamurthy, Bandrehalli Siddagangaiah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(25)N(3)O(5), the central five-membered heterocyclic ring adopts an envelope conformation, with the N atom as the flap. The dihedral angles between this central ring and the pendant indane ring system, the trione and benzene rings are 87.49 (5), 82.95 (10) and 72.42 (10)°, respectively. The dihedral angle between the rings of the biphenyl group is 45.99 (13)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds into [101] C(12) chains. International Union of Crystallography 2014-06-11 /pmc/articles/PMC4120593/ /pubmed/25161552 http://dx.doi.org/10.1107/S1600536814013117 Text en © Subramanyahegde et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Subramanyahegde,
Amar, Hosamani
Shivaraj, Yellappa
Vijayakumar, Giriyapura R.
Palakshamurthy, Bandrehalli Siddagangaiah
5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
title 5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
title_full 5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
title_fullStr 5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
title_full_unstemmed 5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
title_short 5′-([1,1′-Biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
title_sort 5′-([1,1′-biphen­yl]-4-yl)-1′,1′′,3′′-tri­methyl­dispiro[indane-2,2′-pyrrolidine-4′,5′′-[1,3]diazin­ane]-1,3,2′′,4′′,6′′-penta­one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120593/
https://www.ncbi.nlm.nih.gov/pubmed/25161552
http://dx.doi.org/10.1107/S1600536814013117
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