N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide

In the title compound, C(12)H(15)N(3)S, the mol­ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N—N—C—N fragment of −7.04 (16)°. In the crystal, mol­ecules are linked by N—H⋯S hydrogen-...

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Autores principales: Rocha, Fillipe Vieira, de Godoy Netto, Adelino Vieira, Beck, Johannes, Daniels, Jörg, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120594/
https://www.ncbi.nlm.nih.gov/pubmed/25161581
http://dx.doi.org/10.1107/S1600536814013889
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author Rocha, Fillipe Vieira
de Godoy Netto, Adelino Vieira
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
author_facet Rocha, Fillipe Vieira
de Godoy Netto, Adelino Vieira
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
author_sort Rocha, Fillipe Vieira
collection PubMed
description In the title compound, C(12)H(15)N(3)S, the mol­ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N—N—C—N fragment of −7.04 (16)°. In the crystal, mol­ecules are linked by N—H⋯S hydrogen-bond inter­actions, forming centrosymmetric dimers. Additionally, one weak intra­molecular N—H⋯N hydrogen-bond inter­action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis.
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spelling pubmed-41205942014-08-26 N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide Rocha, Fillipe Vieira de Godoy Netto, Adelino Vieira Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(15)N(3)S, the mol­ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N—N—C—N fragment of −7.04 (16)°. In the crystal, mol­ecules are linked by N—H⋯S hydrogen-bond inter­actions, forming centrosymmetric dimers. Additionally, one weak intra­molecular N—H⋯N hydrogen-bond inter­action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120594/ /pubmed/25161581 http://dx.doi.org/10.1107/S1600536814013889 Text en © Rocha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rocha, Fillipe Vieira
de Godoy Netto, Adelino Vieira
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_full N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_fullStr N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_full_unstemmed N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_short N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_sort n-methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120594/
https://www.ncbi.nlm.nih.gov/pubmed/25161581
http://dx.doi.org/10.1107/S1600536814013889
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