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N (1)-[(1H-Imidazol-2-yl)methylidene]-N (4)-phenylbenzene-1,4-diamine
The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, g...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/ https://www.ncbi.nlm.nih.gov/pubmed/25161587 http://dx.doi.org/10.1107/S1600536814014238 |
Sumario: | The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). |
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