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N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine

The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenyl­enedi­amine rings of 30.66 (4)° and between the planes of the phenyl­enedi­amine and N-phenyl rings of 56.63 (7)°. In the crystal, mol­ecules are connected by N—H⋯N hydrogen bonds, g...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Mashrai, Ashraf, Shahid, M., Ahmad, Musheer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/
https://www.ncbi.nlm.nih.gov/pubmed/25161587
http://dx.doi.org/10.1107/S1600536814014238
Descripción
Sumario:The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenyl­enedi­amine rings of 30.66 (4)° and between the planes of the phenyl­enedi­amine and N-phenyl rings of 56.63 (7)°. In the crystal, mol­ecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π inter­actions between N-phenyl and imidazole rings and slipped π–π stacking inter­actions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010).