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N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine

The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenyl­enedi­amine rings of 30.66 (4)° and between the planes of the phenyl­enedi­amine and N-phenyl rings of 56.63 (7)°. In the crystal, mol­ecules are connected by N—H⋯N hydrogen bonds, g...

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Autores principales: Faizi, Md. Serajul Haque, Mashrai, Ashraf, Shahid, M., Ahmad, Musheer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/
https://www.ncbi.nlm.nih.gov/pubmed/25161587
http://dx.doi.org/10.1107/S1600536814014238
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author Faizi, Md. Serajul Haque
Mashrai, Ashraf
Shahid, M.
Ahmad, Musheer
author_facet Faizi, Md. Serajul Haque
Mashrai, Ashraf
Shahid, M.
Ahmad, Musheer
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenyl­enedi­amine rings of 30.66 (4)° and between the planes of the phenyl­enedi­amine and N-phenyl rings of 56.63 (7)°. In the crystal, mol­ecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π inter­actions between N-phenyl and imidazole rings and slipped π–π stacking inter­actions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010).
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spelling pubmed-41205952014-08-26 N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenyl­enedi­amine rings of 30.66 (4)° and between the planes of the phenyl­enedi­amine and N-phenyl rings of 56.63 (7)°. In the crystal, mol­ecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π inter­actions between N-phenyl and imidazole rings and slipped π–π stacking inter­actions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120595/ /pubmed/25161587 http://dx.doi.org/10.1107/S1600536814014238 Text en © Faizi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Faizi, Md. Serajul Haque
Mashrai, Ashraf
Shahid, M.
Ahmad, Musheer
N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_full N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_fullStr N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_full_unstemmed N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_short N (1)-[(1H-Imidazol-2-yl)methyl­idene]-N (4)-phenyl­benzene-1,4-di­amine
title_sort n (1)-[(1h-imidazol-2-yl)methyl­idene]-n (4)-phenyl­benzene-1,4-di­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/
https://www.ncbi.nlm.nih.gov/pubmed/25161587
http://dx.doi.org/10.1107/S1600536814014238
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