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N (1)-[(1H-Imidazol-2-yl)methylidene]-N (4)-phenylbenzene-1,4-diamine
The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, g...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/ https://www.ncbi.nlm.nih.gov/pubmed/25161587 http://dx.doi.org/10.1107/S1600536814014238 |
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author | Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer |
author_facet | Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer |
author_sort | Faizi, Md. Serajul Haque |
collection | PubMed |
description | The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). |
format | Online Article Text |
id | pubmed-4120595 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41205952014-08-26 N (1)-[(1H-Imidazol-2-yl)methylidene]-N (4)-phenylbenzene-1,4-diamine Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(14)N(4), is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120595/ /pubmed/25161587 http://dx.doi.org/10.1107/S1600536814014238 Text en © Faizi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer N (1)-[(1H-Imidazol-2-yl)methylidene]-N (4)-phenylbenzene-1,4-diamine |
title |
N
(1)-[(1H-Imidazol-2-yl)methylidene]-N
(4)-phenylbenzene-1,4-diamine |
title_full |
N
(1)-[(1H-Imidazol-2-yl)methylidene]-N
(4)-phenylbenzene-1,4-diamine |
title_fullStr |
N
(1)-[(1H-Imidazol-2-yl)methylidene]-N
(4)-phenylbenzene-1,4-diamine |
title_full_unstemmed |
N
(1)-[(1H-Imidazol-2-yl)methylidene]-N
(4)-phenylbenzene-1,4-diamine |
title_short |
N
(1)-[(1H-Imidazol-2-yl)methylidene]-N
(4)-phenylbenzene-1,4-diamine |
title_sort | n
(1)-[(1h-imidazol-2-yl)methylidene]-n
(4)-phenylbenzene-1,4-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/ https://www.ncbi.nlm.nih.gov/pubmed/25161587 http://dx.doi.org/10.1107/S1600536814014238 |
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