6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine

In the title mol­ecule, C(22)H(15)Br(2)N(3)O(2)S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)°, respectively, with the mean planes of the thio­phene and two pyridine rings. The dioxane ring is in a half-chair conformation. An intra­molecular C—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: Mitchell, Lauren A., Holliday, Bradley J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120601/
https://www.ncbi.nlm.nih.gov/pubmed/25161578
http://dx.doi.org/10.1107/S1600536814013191
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author Mitchell, Lauren A.
Holliday, Bradley J.
author_facet Mitchell, Lauren A.
Holliday, Bradley J.
author_sort Mitchell, Lauren A.
collection PubMed
description In the title mol­ecule, C(22)H(15)Br(2)N(3)O(2)S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)°, respectively, with the mean planes of the thio­phene and two pyridine rings. The dioxane ring is in a half-chair conformation. An intra­molecular C—H⋯O hydrogen forms an S(6) ring. The amine N atom is sp (2)-hybridized.
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spelling pubmed-41206012014-08-26 6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine Mitchell, Lauren A. Holliday, Bradley J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(22)H(15)Br(2)N(3)O(2)S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)°, respectively, with the mean planes of the thio­phene and two pyridine rings. The dioxane ring is in a half-chair conformation. An intra­molecular C—H⋯O hydrogen forms an S(6) ring. The amine N atom is sp (2)-hybridized. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120601/ /pubmed/25161578 http://dx.doi.org/10.1107/S1600536814013191 Text en © Mitchell and Holliday 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mitchell, Lauren A.
Holliday, Bradley J.
6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
title 6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
title_full 6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
title_fullStr 6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
title_full_unstemmed 6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
title_short 6-Bromo-N-(6-bromo­pyridin-2-yl)-N-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
title_sort 6-bromo-n-(6-bromo­pyridin-2-yl)-n-[4-(2,3-di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)phen­yl]pyridin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120601/
https://www.ncbi.nlm.nih.gov/pubmed/25161578
http://dx.doi.org/10.1107/S1600536814013191
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