fac-[1,2-Bis(pyridin-4-yl)ethane-κN]tricarbon­yl(1,10-phenanthroline-κ(2) N,N′)rhenium(I) hexa­fluorido­phosphate aceto­nitrile monosolvate

The asymmetric unit of the title compound, [Re(C(12)H(8)N(2))(C(12)H(12)N(2))(CO)(3)]PF(6).·CH(3)CN, contains one cation, one hexa­fluorido­phosphate anion and one aceto­nitrile solvent mol­ecule. The Re(I) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand and one N atom from the 1,2-bis­(pyridin-4-yl)ethane ligand [mean Re—N = 2.191 (15) Å] and by three carbonyl ligands [mean Re—C = 1.926 (3) Å] in a distorted octa­hedral geometry. The electrostatic forces and weak C—H⋯F(O) hydrogen bonds pack cations and anions into the crystal with voids of 82 Å(3), which are filled by solvent mol­ecules. The crystal packing exhibits short inter­molecular O⋯O distance of 2.795 (5) Å between two cations related by inversion.