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Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate

In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetra­nuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. T...

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Detalles Bibliográficos
Autores principales: Gubina, Kateryna, Ovchynnikov, Vladimir, Amirkhanov, Vladimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120606/
https://www.ncbi.nlm.nih.gov/pubmed/25161534
http://dx.doi.org/10.1107/S160053681401407X
Descripción
Sumario:In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetra­nuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. The morpholine rings adopt chair conformations, with the N—Cu bonds in equatorial orientations. In the crystal, the components are linked by N—H⋯O and O—H⋯O and O—H⋯Cl hydrogen bonds, which generate a three-dimensional network. One methanol mol­ecule is disordered over two sets of sites in a 0.642 (9):0.358 (9) ratio.