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Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate

In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetra­nuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. T...

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Autores principales: Gubina, Kateryna, Ovchynnikov, Vladimir, Amirkhanov, Vladimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120606/
https://www.ncbi.nlm.nih.gov/pubmed/25161534
http://dx.doi.org/10.1107/S160053681401407X
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author Gubina, Kateryna
Ovchynnikov, Vladimir
Amirkhanov, Vladimir
author_facet Gubina, Kateryna
Ovchynnikov, Vladimir
Amirkhanov, Vladimir
author_sort Gubina, Kateryna
collection PubMed
description In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetra­nuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. The morpholine rings adopt chair conformations, with the N—Cu bonds in equatorial orientations. In the crystal, the components are linked by N—H⋯O and O—H⋯O and O—H⋯Cl hydrogen bonds, which generate a three-dimensional network. One methanol mol­ecule is disordered over two sets of sites in a 0.642 (9):0.358 (9) ratio.
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spelling pubmed-41206062014-08-26 Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate Gubina, Kateryna Ovchynnikov, Vladimir Amirkhanov, Vladimir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetra­nuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. The morpholine rings adopt chair conformations, with the N—Cu bonds in equatorial orientations. In the crystal, the components are linked by N—H⋯O and O—H⋯O and O—H⋯Cl hydrogen bonds, which generate a three-dimensional network. One methanol mol­ecule is disordered over two sets of sites in a 0.642 (9):0.358 (9) ratio. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120606/ /pubmed/25161534 http://dx.doi.org/10.1107/S160053681401407X Text en © Gubina et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gubina, Kateryna
Ovchynnikov, Vladimir
Amirkhanov, Vladimir
Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate
title Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate
title_full Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate
title_fullStr Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate
title_full_unstemmed Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate
title_short Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κN)copper(II)] methanol disolvate
title_sort hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis[(morpholine-κn)copper(ii)] methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120606/
https://www.ncbi.nlm.nih.gov/pubmed/25161534
http://dx.doi.org/10.1107/S160053681401407X
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AT amirkhanovvladimir hexam2chloridom4oxidotetrakismorpholinekncopperiimethanoldisolvate