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Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate
In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetranuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. T...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120606/ https://www.ncbi.nlm.nih.gov/pubmed/25161534 http://dx.doi.org/10.1107/S160053681401407X |
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author | Gubina, Kateryna Ovchynnikov, Vladimir Amirkhanov, Vladimir |
author_facet | Gubina, Kateryna Ovchynnikov, Vladimir Amirkhanov, Vladimir |
author_sort | Gubina, Kateryna |
collection | PubMed |
description | In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetranuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. The morpholine rings adopt chair conformations, with the N—Cu bonds in equatorial orientations. In the crystal, the components are linked by N—H⋯O and O—H⋯O and O—H⋯Cl hydrogen bonds, which generate a three-dimensional network. One methanol molecule is disordered over two sets of sites in a 0.642 (9):0.358 (9) ratio. |
format | Online Article Text |
id | pubmed-4120606 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41206062014-08-26 Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate Gubina, Kateryna Ovchynnikov, Vladimir Amirkhanov, Vladimir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvate, [Cu(4)(μ(2)-Cl)(6)(μ(4)-O)(C(4)H(9)NO)(4)]·2CH(3)OH, each Cu(2+) ion in the tetranuclear complex has a trigonal–bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ(4)-O(2−) ion and morpholine N atom in axial positions. The morpholine rings adopt chair conformations, with the N—Cu bonds in equatorial orientations. In the crystal, the components are linked by N—H⋯O and O—H⋯O and O—H⋯Cl hydrogen bonds, which generate a three-dimensional network. One methanol molecule is disordered over two sets of sites in a 0.642 (9):0.358 (9) ratio. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120606/ /pubmed/25161534 http://dx.doi.org/10.1107/S160053681401407X Text en © Gubina et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gubina, Kateryna Ovchynnikov, Vladimir Amirkhanov, Vladimir Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate |
title | Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate |
title_full | Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate |
title_fullStr | Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate |
title_full_unstemmed | Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate |
title_short | Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate |
title_sort | hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κn)copper(ii)] methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120606/ https://www.ncbi.nlm.nih.gov/pubmed/25161534 http://dx.doi.org/10.1107/S160053681401407X |
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