Cargando…
catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido]
In the title coordination polymer, [MnCl(2)(C(7)H(5)NS)(2)](n), the Mn(II) ion is located on the intersection of a twofold rotation axis and a mirror plane and adopts an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial posit...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120608/ https://www.ncbi.nlm.nih.gov/pubmed/25161533 http://dx.doi.org/10.1107/S1600536814014159 |
_version_ | 1782329118711349248 |
---|---|
author | Bouchareb, Hasna Benmebarek, Sabrina Bouacida, Sofiane Merazig, Hocine Boudraa, Mhamed |
author_facet | Bouchareb, Hasna Benmebarek, Sabrina Bouacida, Sofiane Merazig, Hocine Boudraa, Mhamed |
author_sort | Bouchareb, Hasna |
collection | PubMed |
description | In the title coordination polymer, [MnCl(2)(C(7)H(5)NS)(2)](n), the Mn(II) ion is located on the intersection of a twofold rotation axis and a mirror plane and adopts an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π–π stacking interactions with a centroid–centroid distance of 3.6029 (15) Å. |
format | Online Article Text |
id | pubmed-4120608 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41206082014-08-26 catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] Bouchareb, Hasna Benmebarek, Sabrina Bouacida, Sofiane Merazig, Hocine Boudraa, Mhamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [MnCl(2)(C(7)H(5)NS)(2)](n), the Mn(II) ion is located on the intersection of a twofold rotation axis and a mirror plane and adopts an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π–π stacking interactions with a centroid–centroid distance of 3.6029 (15) Å. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120608/ /pubmed/25161533 http://dx.doi.org/10.1107/S1600536814014159 Text en © Bouchareb et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bouchareb, Hasna Benmebarek, Sabrina Bouacida, Sofiane Merazig, Hocine Boudraa, Mhamed catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] |
title |
catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] |
title_full |
catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] |
title_fullStr |
catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] |
title_full_unstemmed |
catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] |
title_short |
catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido] |
title_sort | catena-poly[[trans-bis(1,3-benzothiazole-κn)manganese(ii)]-di-μ-chlorido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120608/ https://www.ncbi.nlm.nih.gov/pubmed/25161533 http://dx.doi.org/10.1107/S1600536814014159 |
work_keys_str_mv | AT boucharebhasna catenapolytransbis13benzothiazoleknmanganeseiidimchlorido AT benmebareksabrina catenapolytransbis13benzothiazoleknmanganeseiidimchlorido AT bouacidasofiane catenapolytransbis13benzothiazoleknmanganeseiidimchlorido AT merazighocine catenapolytransbis13benzothiazoleknmanganeseiidimchlorido AT boudraamhamed catenapolytransbis13benzothiazoleknmanganeseiidimchlorido |