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catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]

In the title coordination polymer, [MnCl(2)(C(7)H(5)NS)(2)](n), the Mn(II) ion is located on the inter­section of a twofold rotation axis and a mirror plane and adopts an octa­hedral coordination geometry defined by two mutually trans N atoms from benzo­thia­zole ligands which occupy the axial posit...

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Detalles Bibliográficos
Autores principales: Bouchareb, Hasna, Benmebarek, Sabrina, Bouacida, Sofiane, Merazig, Hocine, Boudraa, Mhamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120608/
https://www.ncbi.nlm.nih.gov/pubmed/25161533
http://dx.doi.org/10.1107/S1600536814014159
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author Bouchareb, Hasna
Benmebarek, Sabrina
Bouacida, Sofiane
Merazig, Hocine
Boudraa, Mhamed
author_facet Bouchareb, Hasna
Benmebarek, Sabrina
Bouacida, Sofiane
Merazig, Hocine
Boudraa, Mhamed
author_sort Bouchareb, Hasna
collection PubMed
description In the title coordination polymer, [MnCl(2)(C(7)H(5)NS)(2)](n), the Mn(II) ion is located on the inter­section of a twofold rotation axis and a mirror plane and adopts an octa­hedral coordination geometry defined by two mutually trans N atoms from benzo­thia­zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π–π stacking inter­actions with a centroid–centroid distance of 3.6029 (15) Å.
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spelling pubmed-41206082014-08-26 catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido] Bouchareb, Hasna Benmebarek, Sabrina Bouacida, Sofiane Merazig, Hocine Boudraa, Mhamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [MnCl(2)(C(7)H(5)NS)(2)](n), the Mn(II) ion is located on the inter­section of a twofold rotation axis and a mirror plane and adopts an octa­hedral coordination geometry defined by two mutually trans N atoms from benzo­thia­zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π–π stacking inter­actions with a centroid–centroid distance of 3.6029 (15) Å. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120608/ /pubmed/25161533 http://dx.doi.org/10.1107/S1600536814014159 Text en © Bouchareb et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouchareb, Hasna
Benmebarek, Sabrina
Bouacida, Sofiane
Merazig, Hocine
Boudraa, Mhamed
catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]
title catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]
title_full catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]
title_fullStr catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]
title_full_unstemmed catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]
title_short catena-Poly[[trans-bis­(1,3-benzo­thia­zole-κN)manganese(II)]-di-μ-chlorido]
title_sort catena-poly[[trans-bis­(1,3-benzo­thia­zole-κn)manganese(ii)]-di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120608/
https://www.ncbi.nlm.nih.gov/pubmed/25161533
http://dx.doi.org/10.1107/S1600536814014159
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