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6-Iodo-4-oxo-4H-chromene-3-carbaldehyde
In the title compound, C(10)H(5)IO(3), an iodinated 3-formylchromone derivative, the non-H atoms are essentially coplanar (r.m.s. deviation = 0.0259 Å), with the largest deviation from the least-squares plane [0.056 (5) Å] being found for the formyl O atom. In the crystal, molecules are linked thr...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120610/ https://www.ncbi.nlm.nih.gov/pubmed/25161541 http://dx.doi.org/10.1107/S1600536814012471 |
Sumario: | In the title compound, C(10)H(5)IO(3), an iodinated 3-formylchromone derivative, the non-H atoms are essentially coplanar (r.m.s. deviation = 0.0259 Å), with the largest deviation from the least-squares plane [0.056 (5) Å] being found for the formyl O atom. In the crystal, molecules are linked through I⋯O halogen bonds [I⋯O = 3.245 (4) Å, C—I⋯O = 165.95 (13) and C=O⋯I = 169.7 (4)°] along [101]. The supramolecular chains are assembled into layers via π–π stacking interactions along the b axis [shortest centroid–centroid distance between the pyran and benzene rings = 3.558 (3) Å]. |
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