β-K(3)Fe(MoO(4))(2)Mo(2)O(7)

The title compound, tripotassium iron(III) bis­(ortho­molyb­date) dimolybdate, was obtained by a solid-state reaction. The main structural building units are one FeO(6) octa­hedron, two MoO(4) tetra­hedra and one Mo(2)O(7) dimolybdate group, all with point group symmetries m. These units are linked...

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Detalles Bibliográficos
Autores principales: Souilem, Amira, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120611/
https://www.ncbi.nlm.nih.gov/pubmed/25161509
http://dx.doi.org/10.1107/S1600536814013087
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author Souilem, Amira
Zid, Mohamed Faouzi
Driss, Ahmed
author_facet Souilem, Amira
Zid, Mohamed Faouzi
Driss, Ahmed
author_sort Souilem, Amira
collection PubMed
description The title compound, tripotassium iron(III) bis­(ortho­molyb­date) dimolybdate, was obtained by a solid-state reaction. The main structural building units are one FeO(6) octa­hedron, two MoO(4) tetra­hedra and one Mo(2)O(7) dimolybdate group, all with point group symmetries m. These units are linked via corner-sharing to form ribbons parallel to [010]. The three K(+) cations are located between the ribbons on mirror planes and have coordination numbers of 10 and 12. Two O atoms of one of the MoO(4) tetra­hedra of the dimolybdate group are disordered over two positions in a 0.524 (11):0.476 (11) ratio. The structure of the title compound is compared briefly with that of Rb(3)FeMo(4)O(15).
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spelling pubmed-41206112014-08-26 β-K(3)Fe(MoO(4))(2)Mo(2)O(7) Souilem, Amira Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, tripotassium iron(III) bis­(ortho­molyb­date) dimolybdate, was obtained by a solid-state reaction. The main structural building units are one FeO(6) octa­hedron, two MoO(4) tetra­hedra and one Mo(2)O(7) dimolybdate group, all with point group symmetries m. These units are linked via corner-sharing to form ribbons parallel to [010]. The three K(+) cations are located between the ribbons on mirror planes and have coordination numbers of 10 and 12. Two O atoms of one of the MoO(4) tetra­hedra of the dimolybdate group are disordered over two positions in a 0.524 (11):0.476 (11) ratio. The structure of the title compound is compared briefly with that of Rb(3)FeMo(4)O(15). International Union of Crystallography 2014-06-11 /pmc/articles/PMC4120611/ /pubmed/25161509 http://dx.doi.org/10.1107/S1600536814013087 Text en © Souilem et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Souilem, Amira
Zid, Mohamed Faouzi
Driss, Ahmed
β-K(3)Fe(MoO(4))(2)Mo(2)O(7)
title β-K(3)Fe(MoO(4))(2)Mo(2)O(7)
title_full β-K(3)Fe(MoO(4))(2)Mo(2)O(7)
title_fullStr β-K(3)Fe(MoO(4))(2)Mo(2)O(7)
title_full_unstemmed β-K(3)Fe(MoO(4))(2)Mo(2)O(7)
title_short β-K(3)Fe(MoO(4))(2)Mo(2)O(7)
title_sort β-k(3)fe(moo(4))(2)mo(2)o(7)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120611/
https://www.ncbi.nlm.nih.gov/pubmed/25161509
http://dx.doi.org/10.1107/S1600536814013087
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AT zidmohamedfaouzi bk3femoo42mo2o7
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