(N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate

In the title salt, [Ag(C(7)H(8)N(2)S)(C(18)H(15)P)(2)]NO(3), the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, g...

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Detalles Bibliográficos
Autores principales: Mekarat, Sofia, Pakawatchai, Chaveng, Saithong, Saowanit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120613/
https://www.ncbi.nlm.nih.gov/pubmed/25161537
http://dx.doi.org/10.1107/S1600536814014147
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author Mekarat, Sofia
Pakawatchai, Chaveng
Saithong, Saowanit
author_facet Mekarat, Sofia
Pakawatchai, Chaveng
Saithong, Saowanit
author_sort Mekarat, Sofia
collection PubMed
description In the title salt, [Ag(C(7)H(8)N(2)S)(C(18)H(15)P)(2)]NO(3), the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, generating tetra­mers (two cations and two anions), which feature R (2) (2)(8) and R (4) (4)(8) loops. The cations are linked by weak C—H⋯π inter­actions, generating a three-dimensional network.
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spelling pubmed-41206132014-08-26 (N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate Mekarat, Sofia Pakawatchai, Chaveng Saithong, Saowanit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Ag(C(7)H(8)N(2)S)(C(18)H(15)P)(2)]NO(3), the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, generating tetra­mers (two cations and two anions), which feature R (2) (2)(8) and R (4) (4)(8) loops. The cations are linked by weak C—H⋯π inter­actions, generating a three-dimensional network. International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120613/ /pubmed/25161537 http://dx.doi.org/10.1107/S1600536814014147 Text en © Mekarat et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mekarat, Sofia
Pakawatchai, Chaveng
Saithong, Saowanit
(N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title (N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_full (N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_fullStr (N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_full_unstemmed (N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_short (N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_sort (n-phenyl­thio­urea-κs)bis­(tri­phenylphosphane-κp)silver(i) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120613/
https://www.ncbi.nlm.nih.gov/pubmed/25161537
http://dx.doi.org/10.1107/S1600536814014147
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