2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene

In the title compound, C(18)H(12)F(4)N(2)S(2), a bis-thio­phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry. The thio­phene and tetra­fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°. The...

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Detalles Bibliográficos
Autores principales: Gao, Ning, Luo, Hai-Kun, Qin, Rui-Rui, He, Ming-Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120615/
https://www.ncbi.nlm.nih.gov/pubmed/25161544
http://dx.doi.org/10.1107/S1600536814012434
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author Gao, Ning
Luo, Hai-Kun
Qin, Rui-Rui
He, Ming-Yang
author_facet Gao, Ning
Luo, Hai-Kun
Qin, Rui-Rui
He, Ming-Yang
author_sort Gao, Ning
collection PubMed
description In the title compound, C(18)H(12)F(4)N(2)S(2), a bis-thio­phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry. The thio­phene and tetra­fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°. The crystal structure exhibits C—H⋯F hydrogen bonds, resulting in supra­molecular chains along the c-axis direction.
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spelling pubmed-41206152014-08-26 2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene Gao, Ning Luo, Hai-Kun Qin, Rui-Rui He, Ming-Yang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(12)F(4)N(2)S(2), a bis-thio­phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry. The thio­phene and tetra­fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°. The crystal structure exhibits C—H⋯F hydrogen bonds, resulting in supra­molecular chains along the c-axis direction. International Union of Crystallography 2014-06-04 /pmc/articles/PMC4120615/ /pubmed/25161544 http://dx.doi.org/10.1107/S1600536814012434 Text en © Gao et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Ning
Luo, Hai-Kun
Qin, Rui-Rui
He, Ming-Yang
2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title 2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_full 2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_fullStr 2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_full_unstemmed 2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_short 2,3,5,6-Tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_sort 2,3,5,6-tetra­fluoro-1,4-bis­({[(thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120615/
https://www.ncbi.nlm.nih.gov/pubmed/25161544
http://dx.doi.org/10.1107/S1600536814012434
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AT luohaikun 2356tetrafluoro14bisthiophen2ylmethylideneaminomethylbenzene
AT qinruirui 2356tetrafluoro14bisthiophen2ylmethylideneaminomethylbenzene
AT hemingyang 2356tetrafluoro14bisthiophen2ylmethylideneaminomethylbenzene

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