(η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate

The title compound, [RuCl(2)(η(6)-C(6)H(6))(C(12)H(22)ClP)]·CHCl(3), was prepared by reaction of [RuCl(2)(η(6)-C(6)H(6))](2) with chloro­dicyclo­hexyl­phosphane in CHCl(3) at 323 K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool ge...

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Detalles Bibliográficos
Autores principales: Gowrisankar, Saravanan, Neumann, Helfried, Spannenberg, Anke, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120624/
https://www.ncbi.nlm.nih.gov/pubmed/25161521
http://dx.doi.org/10.1107/S1600536814012975
Descripción
Sumario:The title compound, [RuCl(2)(η(6)-C(6)H(6))(C(12)H(22)ClP)]·CHCl(3), was prepared by reaction of [RuCl(2)(η(6)-C(6)H(6))](2) with chloro­dicyclo­hexyl­phosphane in CHCl(3) at 323 K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru—P bond length of 2.3247 (4) Å. Both cyclo­hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol­ecule and the chloro­form solvent mol­ecule are linked by a bifurcated C—H⋯(Cl,Cl) hydrogen bond. Intra­molecular C—H⋯Cl hydrogen bonds are also observed.

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