(η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate

The title compound, [RuCl(2)(η(6)-C(6)H(6))(C(12)H(22)ClP)]·CHCl(3), was prepared by reaction of [RuCl(2)(η(6)-C(6)H(6))](2) with chloro­dicyclo­hexyl­phosphane in CHCl(3) at 323 K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool ge...

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Autores principales: Gowrisankar, Saravanan, Neumann, Helfried, Spannenberg, Anke, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120624/
https://www.ncbi.nlm.nih.gov/pubmed/25161521
http://dx.doi.org/10.1107/S1600536814012975
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author Gowrisankar, Saravanan
Neumann, Helfried
Spannenberg, Anke
Beller, Matthias
author_facet Gowrisankar, Saravanan
Neumann, Helfried
Spannenberg, Anke
Beller, Matthias
author_sort Gowrisankar, Saravanan
collection PubMed
description The title compound, [RuCl(2)(η(6)-C(6)H(6))(C(12)H(22)ClP)]·CHCl(3), was prepared by reaction of [RuCl(2)(η(6)-C(6)H(6))](2) with chloro­dicyclo­hexyl­phosphane in CHCl(3) at 323 K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru—P bond length of 2.3247 (4) Å. Both cyclo­hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol­ecule and the chloro­form solvent mol­ecule are linked by a bifurcated C—H⋯(Cl,Cl) hydrogen bond. Intra­molecular C—H⋯Cl hydrogen bonds are also observed.
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spelling pubmed-41206242014-08-26 (η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate Gowrisankar, Saravanan Neumann, Helfried Spannenberg, Anke Beller, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [RuCl(2)(η(6)-C(6)H(6))(C(12)H(22)ClP)]·CHCl(3), was prepared by reaction of [RuCl(2)(η(6)-C(6)H(6))](2) with chloro­dicyclo­hexyl­phosphane in CHCl(3) at 323 K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru—P bond length of 2.3247 (4) Å. Both cyclo­hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol­ecule and the chloro­form solvent mol­ecule are linked by a bifurcated C—H⋯(Cl,Cl) hydrogen bond. Intra­molecular C—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2014-06-11 /pmc/articles/PMC4120624/ /pubmed/25161521 http://dx.doi.org/10.1107/S1600536814012975 Text en © Gowrisankar et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowrisankar, Saravanan
Neumann, Helfried
Spannenberg, Anke
Beller, Matthias
(η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate
title (η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate
title_full (η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate
title_fullStr (η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate
title_full_unstemmed (η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate
title_short (η(6)-Benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κP)ruthenium(II) chloro­form monosolvate
title_sort (η(6)-benzene)­dichlorido­(chloro­dicyclo­hexyl­phosphane-κp)ruthenium(ii) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120624/
https://www.ncbi.nlm.nih.gov/pubmed/25161521
http://dx.doi.org/10.1107/S1600536814012975
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AT neumannhelfried ē6benzenedichloridochlorodicyclohexylphosphanekprutheniumiichloroformmonosolvate
AT spannenberganke ē6benzenedichloridochlorodicyclohexylphosphanekprutheniumiichloroformmonosolvate
AT bellermatthias ē6benzenedichloridochlorodicyclohexylphosphanekprutheniumiichloroformmonosolvate

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