N-Methyl-N-nitroso-p-toluene­sulfon­amide

The crystal structure of the title compound, C(8)H(10)N(2)O(3)S, displays predominant C—H⋯O hydrogen-bonding and π–π stacking inter­actions. The hydrogen bonds are between the O atoms of the sulfonyl group and H atoms on methyl groups. The π–π stacking inter­actions occur between adjacent aromatic r...

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Detalles Bibliográficos
Autores principales: Rai, Kartik, Wu, Vincent, Gupta, Priya, Laviska, David A., Chan, Benny C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120625/
https://www.ncbi.nlm.nih.gov/pubmed/25161568
http://dx.doi.org/10.1107/S1600536814013518
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author Rai, Kartik
Wu, Vincent
Gupta, Priya
Laviska, David A.
Chan, Benny C.
author_facet Rai, Kartik
Wu, Vincent
Gupta, Priya
Laviska, David A.
Chan, Benny C.
author_sort Rai, Kartik
collection PubMed
description The crystal structure of the title compound, C(8)H(10)N(2)O(3)S, displays predominant C—H⋯O hydrogen-bonding and π–π stacking inter­actions. The hydrogen bonds are between the O atoms of the sulfonyl group and H atoms on methyl groups. The π–π stacking inter­actions occur between adjacent aromatic rings, with a centroid–centroid distance of 3.868 (11) Å. These inter­actions lead to the formation of chains parallel to (101).
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spelling pubmed-41206252014-08-26 N-Methyl-N-nitroso-p-toluene­sulfon­amide Rai, Kartik Wu, Vincent Gupta, Priya Laviska, David A. Chan, Benny C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(8)H(10)N(2)O(3)S, displays predominant C—H⋯O hydrogen-bonding and π–π stacking inter­actions. The hydrogen bonds are between the O atoms of the sulfonyl group and H atoms on methyl groups. The π–π stacking inter­actions occur between adjacent aromatic rings, with a centroid–centroid distance of 3.868 (11) Å. These inter­actions lead to the formation of chains parallel to (101). International Union of Crystallography 2014-06-14 /pmc/articles/PMC4120625/ /pubmed/25161568 http://dx.doi.org/10.1107/S1600536814013518 Text en © Rai et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rai, Kartik
Wu, Vincent
Gupta, Priya
Laviska, David A.
Chan, Benny C.
N-Methyl-N-nitroso-p-toluene­sulfon­amide
title N-Methyl-N-nitroso-p-toluene­sulfon­amide
title_full N-Methyl-N-nitroso-p-toluene­sulfon­amide
title_fullStr N-Methyl-N-nitroso-p-toluene­sulfon­amide
title_full_unstemmed N-Methyl-N-nitroso-p-toluene­sulfon­amide
title_short N-Methyl-N-nitroso-p-toluene­sulfon­amide
title_sort n-methyl-n-nitroso-p-toluene­sulfon­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120625/
https://www.ncbi.nlm.nih.gov/pubmed/25161568
http://dx.doi.org/10.1107/S1600536814013518
work_keys_str_mv AT raikartik nmethylnnitrosoptoluenesulfonamide
AT wuvincent nmethylnnitrosoptoluenesulfonamide
AT guptapriya nmethylnnitrosoptoluenesulfonamide
AT laviskadavida nmethylnnitrosoptoluenesulfonamide
AT chanbennyc nmethylnnitrosoptoluenesulfonamide

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