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Bis(4-aminopyridinium) dichromate(VI)
The asymmetric unit of the title salt, (C(5)H(7)N(2))(2)[Cr(2)O(7)], contains four independent cations and two independent dichromate anions. The crystal structure consists of discrete dichromate anions with an eclipsed conformation stacked in layers parallel to (010) at y = 1/4 and y = 3/4. These l...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120631/ https://www.ncbi.nlm.nih.gov/pubmed/25161526 http://dx.doi.org/10.1107/S1600536814013579 |
Sumario: | The asymmetric unit of the title salt, (C(5)H(7)N(2))(2)[Cr(2)O(7)], contains four independent cations and two independent dichromate anions. The crystal structure consists of discrete dichromate anions with an eclipsed conformation stacked in layers parallel to (010) at y = 1/4 and y = 3/4. These layers are linked via 4-aminopyridinium cations by N—H⋯O and weak C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. In addition, π–π interactions are present in this structure; the shortest distance separating mean planes through 4-aminopyridinium cations is 3.679 (6) Å. |
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