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Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate

The title compound, C(25)H(27)NO(4), has a flattened di­hydro­pyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di­hydro­pyridine ring. In the crystal, N—H⋯O h...

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Detalles Bibliográficos
Autores principales: Steiger, Scott A., Monacelli, Anthony J., Li, Chun, Hunting, Janet L., Natale, Nicholas R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120632/
https://www.ncbi.nlm.nih.gov/pubmed/25161575
http://dx.doi.org/10.1107/S1600536814013294
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author Steiger, Scott A.
Monacelli, Anthony J.
Li, Chun
Hunting, Janet L.
Natale, Nicholas R.
author_facet Steiger, Scott A.
Monacelli, Anthony J.
Li, Chun
Hunting, Janet L.
Natale, Nicholas R.
author_sort Steiger, Scott A.
collection PubMed
description The title compound, C(25)H(27)NO(4), has a flattened di­hydro­pyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di­hydro­pyridine ring. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into chain motifs running along the a-axis direction. The chains are cross-linked by C—H⋯O inter­actions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intra­molecular C—H⋯O hydrogen bonds are also observed.
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spelling pubmed-41206322014-08-26 Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate Steiger, Scott A. Monacelli, Anthony J. Li, Chun Hunting, Janet L. Natale, Nicholas R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(27)NO(4), has a flattened di­hydro­pyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di­hydro­pyridine ring. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into chain motifs running along the a-axis direction. The chains are cross-linked by C—H⋯O inter­actions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intra­molecular C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2014-06-18 /pmc/articles/PMC4120632/ /pubmed/25161575 http://dx.doi.org/10.1107/S1600536814013294 Text en © Steiger et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Steiger, Scott A.
Monacelli, Anthony J.
Li, Chun
Hunting, Janet L.
Natale, Nicholas R.
Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
title Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
title_full Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
title_fullStr Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
title_full_unstemmed Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
title_short Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
title_sort diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di­hydro­pyridine-3,5-di­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120632/
https://www.ncbi.nlm.nih.gov/pubmed/25161575
http://dx.doi.org/10.1107/S1600536814013294
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