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8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde

In the title compound, C(10)H(5)FO(3), the non-H atoms of the 8-fluoro­chromone unit are essentially coplanar (r.m.s. deviation = 0.0259 Å), with a largest deviation from the mean plane of 0.0660 (12) Å for the chromone carbonyl O atom. The formyl group is twisted with respect to the attached ring [...

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Autor principal: Ishikawa, Yoshinobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120633/
https://www.ncbi.nlm.nih.gov/pubmed/25161562
http://dx.doi.org/10.1107/S1600536814013208
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author Ishikawa, Yoshinobu
author_facet Ishikawa, Yoshinobu
author_sort Ishikawa, Yoshinobu
collection PubMed
description In the title compound, C(10)H(5)FO(3), the non-H atoms of the 8-fluoro­chromone unit are essentially coplanar (r.m.s. deviation = 0.0259 Å), with a largest deviation from the mean plane of 0.0660 (12) Å for the chromone carbonyl O atom. The formyl group is twisted with respect to the attached ring [C—C—C—O torsion angles = −11.00 (19) and 170.81 (11)°]. In the crystal, mol­ecules are linked via weak C—H⋯O hydrogen bonds along the a axis and [-101], forming corrugated layers parallel to (010). In addition, π–π stacking inter­actions [centroid–centroid distance between the planes of the pyran and benzene rings = 3.519 (2) Å] are observed between these layers.
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spelling pubmed-41206332014-08-26 8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde Ishikawa, Yoshinobu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(5)FO(3), the non-H atoms of the 8-fluoro­chromone unit are essentially coplanar (r.m.s. deviation = 0.0259 Å), with a largest deviation from the mean plane of 0.0660 (12) Å for the chromone carbonyl O atom. The formyl group is twisted with respect to the attached ring [C—C—C—O torsion angles = −11.00 (19) and 170.81 (11)°]. In the crystal, mol­ecules are linked via weak C—H⋯O hydrogen bonds along the a axis and [-101], forming corrugated layers parallel to (010). In addition, π–π stacking inter­actions [centroid–centroid distance between the planes of the pyran and benzene rings = 3.519 (2) Å] are observed between these layers. International Union of Crystallography 2014-06-14 /pmc/articles/PMC4120633/ /pubmed/25161562 http://dx.doi.org/10.1107/S1600536814013208 Text en © Yoshinobu Ishikawa 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ishikawa, Yoshinobu
8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde
title 8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde
title_full 8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde
title_fullStr 8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde
title_full_unstemmed 8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde
title_short 8-Fluoro-4-oxo-4H-chromene-3-carbalde­hyde
title_sort 8-fluoro-4-oxo-4h-chromene-3-carbalde­hyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120633/
https://www.ncbi.nlm.nih.gov/pubmed/25161562
http://dx.doi.org/10.1107/S1600536814013208
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