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(E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate
In the title hydrate, C(19)H(16)N(2)O(4)·H(2)O, the 4H-chromen-4-one segment is slightly twisted, with a dihedral angle between the two six-membered rings of 3.30 (5)°. The dihedral angles between the plane of the pyranone ring and the hydrazide plane and between the planes of the pyranone ring an...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120634/ https://www.ncbi.nlm.nih.gov/pubmed/25161570 http://dx.doi.org/10.1107/S1600536814013713 |
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author | Ishikawa, Yoshinobu Watanabe, Kohzoh |
author_facet | Ishikawa, Yoshinobu Watanabe, Kohzoh |
author_sort | Ishikawa, Yoshinobu |
collection | PubMed |
description | In the title hydrate, C(19)H(16)N(2)O(4)·H(2)O, the 4H-chromen-4-one segment is slightly twisted, with a dihedral angle between the two six-membered rings of 3.30 (5)°. The dihedral angles between the plane of the pyranone ring and the hydrazide plane and between the planes of the pyranone ring and the benzene ring of the p-methoxybenzene unit are 26.69 (4) and 2.23 (3)°, respectively. The molecule is connected to the solvent water molecule by an N—H⋯O hydrogen bond. In the crystal, there are π–π stacking interactions between centrosymmetrically related pyranone rings [centroid–centroid distance = 3.5394 (9) Å], as well as bridges formed by the water molecules via O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-4120634 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41206342014-08-26 (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate Ishikawa, Yoshinobu Watanabe, Kohzoh Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrate, C(19)H(16)N(2)O(4)·H(2)O, the 4H-chromen-4-one segment is slightly twisted, with a dihedral angle between the two six-membered rings of 3.30 (5)°. The dihedral angles between the plane of the pyranone ring and the hydrazide plane and between the planes of the pyranone ring and the benzene ring of the p-methoxybenzene unit are 26.69 (4) and 2.23 (3)°, respectively. The molecule is connected to the solvent water molecule by an N—H⋯O hydrogen bond. In the crystal, there are π–π stacking interactions between centrosymmetrically related pyranone rings [centroid–centroid distance = 3.5394 (9) Å], as well as bridges formed by the water molecules via O—H⋯O hydrogen bonds. International Union of Crystallography 2014-06-18 /pmc/articles/PMC4120634/ /pubmed/25161570 http://dx.doi.org/10.1107/S1600536814013713 Text en © Ishikawa and Watanabe 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ishikawa, Yoshinobu Watanabe, Kohzoh (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title | (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_full | (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_fullStr | (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_full_unstemmed | (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_short | (E)-4-Methoxy-N′-[(6-methyl-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_sort | (e)-4-methoxy-n′-[(6-methyl-4-oxo-4h-chromen-3-yl)methylidene]benzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120634/ https://www.ncbi.nlm.nih.gov/pubmed/25161570 http://dx.doi.org/10.1107/S1600536814013713 |
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