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catena-Poly[[bis(dicyanamido-κN (1))cobalt(II)]bis{μ-1,2-bis[(1,2,4-triazol-1-yl)methyl]benzene-κ(2) N (4):N (4′)}]
In the title complex, [Co(C(2)N(3))(2)(C(12)H(12)N(6))(2)](n) the Co(II) atom lies on a centre of symmetry and displays a slightly distorted octahedral coordination geometry. The 1,2-bis[(1,2,4-triazol-1-yl)methyl]benzene ligands link adjacent metal atoms into polymeric chains parallel to the c a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120635/ https://www.ncbi.nlm.nih.gov/pubmed/25161514 http://dx.doi.org/10.1107/S1600536814012331 |
Sumario: | In the title complex, [Co(C(2)N(3))(2)(C(12)H(12)N(6))(2)](n) the Co(II) atom lies on a centre of symmetry and displays a slightly distorted octahedral coordination geometry. The 1,2-bis[(1,2,4-triazol-1-yl)methyl]benzene ligands link adjacent metal atoms into polymeric chains parallel to the c axis, forming centrosymmetric 26-membered metallamacrocycles. The conformation of the metallamacrocycles is stabilized by pairs of C—H⋯N hydrogen bonds. The dihedral angles formed by the planes of the triazole rings with those of the benzene ring are 79.4 (2) and 79.1 (2)°. In the crystal, the chains interact through C—H⋯N hydrogen bonds, forming a three-dimensional network. |
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