Tetra­amminepalladium(II) dichloride ammonia tetra­solvate

The title compound, [Pd(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt Pd(en)Cl(2) (en is ethylenediamine) and is isotypic with [Pt(NH(3))(4)]Cl(2)·4NH(3) [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol­ecules, exhi...

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Detalles Bibliográficos
Autores principales: Grassl, Tobias, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120636/
https://www.ncbi.nlm.nih.gov/pubmed/25161505
http://dx.doi.org/10.1107/S1600536814012355
Descripción
Sumario:The title compound, [Pd(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt Pd(en)Cl(2) (en is ethylenediamine) and is isotypic with [Pt(NH(3))(4)]Cl(2)·4NH(3) [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol­ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol­ecules. These are either bound in the palladium complex or solvent mol­ecules. The packing of the ammonia solvent mol­ecules enables the formation of an extended network of N—H⋯N and N—H⋯Cl inter­actions with nearly ideal hydrogen-bonding geometry.

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