Tetra­amminepalladium(II) dichloride ammonia tetra­solvate

The title compound, [Pd(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt Pd(en)Cl(2) (en is ethylenediamine) and is isotypic with [Pt(NH(3))(4)]Cl(2)·4NH(3) [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol­ecules, exhi...

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Detalles Bibliográficos
Autores principales: Grassl, Tobias, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120636/
https://www.ncbi.nlm.nih.gov/pubmed/25161505
http://dx.doi.org/10.1107/S1600536814012355
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author Grassl, Tobias
Korber, Nikolaus
author_facet Grassl, Tobias
Korber, Nikolaus
author_sort Grassl, Tobias
collection PubMed
description The title compound, [Pd(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt Pd(en)Cl(2) (en is ethylenediamine) and is isotypic with [Pt(NH(3))(4)]Cl(2)·4NH(3) [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol­ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol­ecules. These are either bound in the palladium complex or solvent mol­ecules. The packing of the ammonia solvent mol­ecules enables the formation of an extended network of N—H⋯N and N—H⋯Cl inter­actions with nearly ideal hydrogen-bonding geometry.
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spelling pubmed-41206362014-08-26 Tetra­amminepalladium(II) dichloride ammonia tetra­solvate Grassl, Tobias Korber, Nikolaus Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, [Pd(NH(3))(4)]Cl(2)·4NH(3), was crystallized in liquid ammonia from the salt Pd(en)Cl(2) (en is ethylenediamine) and is isotypic with [Pt(NH(3))(4)]Cl(2)·4NH(3) [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol­ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol­ecules. These are either bound in the palladium complex or solvent mol­ecules. The packing of the ammonia solvent mol­ecules enables the formation of an extended network of N—H⋯N and N—H⋯Cl inter­actions with nearly ideal hydrogen-bonding geometry. International Union of Crystallography 2014-06-07 /pmc/articles/PMC4120636/ /pubmed/25161505 http://dx.doi.org/10.1107/S1600536814012355 Text en © Grassl and Korber 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Grassl, Tobias
Korber, Nikolaus
Tetra­amminepalladium(II) dichloride ammonia tetra­solvate
title Tetra­amminepalladium(II) dichloride ammonia tetra­solvate
title_full Tetra­amminepalladium(II) dichloride ammonia tetra­solvate
title_fullStr Tetra­amminepalladium(II) dichloride ammonia tetra­solvate
title_full_unstemmed Tetra­amminepalladium(II) dichloride ammonia tetra­solvate
title_short Tetra­amminepalladium(II) dichloride ammonia tetra­solvate
title_sort tetra­amminepalladium(ii) dichloride ammonia tetra­solvate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120636/
https://www.ncbi.nlm.nih.gov/pubmed/25161505
http://dx.doi.org/10.1107/S1600536814012355
work_keys_str_mv AT grassltobias tetraamminepalladiumiidichlorideammoniatetrasolvate
AT korbernikolaus tetraamminepalladiumiidichlorideammoniatetrasolvate

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