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Poly[[tris(μ(2)-acetato-κ(2) O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octahedrally and tetrahedrally coordinated Zn(2+) ions. The octahedral coordination sphere is composed of one N atom of the monodentate diaminochlorobenzene ligand, three acetate O atoms and two bri...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120637/ https://www.ncbi.nlm.nih.gov/pubmed/25161516 http://dx.doi.org/10.1107/S1600536814012641 |
Sumario: | The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octahedrally and tetrahedrally coordinated Zn(2+) ions. The octahedral coordination sphere is composed of one N atom of the monodentate diaminochlorobenzene ligand, three acetate O atoms and two bridging hydroxide ligands. The tetrahedral coordination sphere consists of three acetate O atoms and the hydroxide ligand. The zinc ions are bridged by acetate and hydroxide ligands. The result is a laddered-chain structure parallel to [100] with ethanol solvent molecules occupying the space between the chains. The diamine ligand chlorine substitutent is disordered over two equally populated positions as a result of a crystallographically imposed inversion center between adjacent ligands. The ethanol solvent molecule exhibits disorder with the two components having refined occupancies of 0.696 (11) and 0.304 (11). O—H⋯O hydrogen bonds form between the hydroxide ligand and the ethanol solvent molecule. N—H⋯O and N—H⋯N hydrogen bonding between the uncoordinated amine group and the acetate ligands and the coordinated amine group are also observed. |
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