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Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]

The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octa­hedrally and tetra­hedrally coordinated Zn(2+) ions. The octa­hedral coordination sphere is composed of one N atom of the monodentate di­amino­chloro­benzene ligand, three acetate O atoms and two bri...

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Autores principales: Geiger, David K., Parsons, Dylan E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120637/
https://www.ncbi.nlm.nih.gov/pubmed/25161516
http://dx.doi.org/10.1107/S1600536814012641
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author Geiger, David K.
Parsons, Dylan E.
author_facet Geiger, David K.
Parsons, Dylan E.
author_sort Geiger, David K.
collection PubMed
description The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octa­hedrally and tetra­hedrally coordinated Zn(2+) ions. The octa­hedral coordination sphere is composed of one N atom of the monodentate di­amino­chloro­benzene ligand, three acetate O atoms and two bridging hydroxide ligands. The tetra­hedral coordination sphere consists of three acetate O atoms and the hydroxide ligand. The zinc ions are bridged by acetate and hydroxide ligands. The result is a laddered-chain structure parallel to [100] with ethanol solvent mol­ecules occupying the space between the chains. The di­amine ligand chlorine substitutent is disordered over two equally populated positions as a result of a crystallographically imposed inversion center between adjacent ligands. The ethanol solvent mol­ecule exhibits disorder with the two components having refined occupancies of 0.696 (11) and 0.304 (11). O—H⋯O hydrogen bonds form between the hydroxide ligand and the ethanol solvent mol­ecule. N—H⋯O and N—H⋯N hydrogen bonding between the uncoordinated amine group and the acetate ligands and the coordinated amine group are also observed.
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spelling pubmed-41206372014-08-26 Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] Geiger, David K. Parsons, Dylan E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octa­hedrally and tetra­hedrally coordinated Zn(2+) ions. The octa­hedral coordination sphere is composed of one N atom of the monodentate di­amino­chloro­benzene ligand, three acetate O atoms and two bridging hydroxide ligands. The tetra­hedral coordination sphere consists of three acetate O atoms and the hydroxide ligand. The zinc ions are bridged by acetate and hydroxide ligands. The result is a laddered-chain structure parallel to [100] with ethanol solvent mol­ecules occupying the space between the chains. The di­amine ligand chlorine substitutent is disordered over two equally populated positions as a result of a crystallographically imposed inversion center between adjacent ligands. The ethanol solvent mol­ecule exhibits disorder with the two components having refined occupancies of 0.696 (11) and 0.304 (11). O—H⋯O hydrogen bonds form between the hydroxide ligand and the ethanol solvent mol­ecule. N—H⋯O and N—H⋯N hydrogen bonding between the uncoordinated amine group and the acetate ligands and the coordinated amine group are also observed. International Union of Crystallography 2014-06-07 /pmc/articles/PMC4120637/ /pubmed/25161516 http://dx.doi.org/10.1107/S1600536814012641 Text en © Geiger and Parsons 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Geiger, David K.
Parsons, Dylan E.
Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
title Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
title_full Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
title_fullStr Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
title_full_unstemmed Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
title_short Poly[[tris­(μ(2)-acetato-κ(2) O:O′)(4-chloro­benzene-1,2-di­amine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
title_sort poly[[tris­(μ(2)-acetato-κ(2) o:o′)(4-chloro­benzene-1,2-di­amine-κn)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120637/
https://www.ncbi.nlm.nih.gov/pubmed/25161516
http://dx.doi.org/10.1107/S1600536814012641
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