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Poly[[tris(μ(2)-acetato-κ(2) O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate]
The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octahedrally and tetrahedrally coordinated Zn(2+) ions. The octahedral coordination sphere is composed of one N atom of the monodentate diaminochlorobenzene ligand, three acetate O atoms and two bri...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120637/ https://www.ncbi.nlm.nih.gov/pubmed/25161516 http://dx.doi.org/10.1107/S1600536814012641 |
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author | Geiger, David K. Parsons, Dylan E. |
author_facet | Geiger, David K. Parsons, Dylan E. |
author_sort | Geiger, David K. |
collection | PubMed |
description | The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octahedrally and tetrahedrally coordinated Zn(2+) ions. The octahedral coordination sphere is composed of one N atom of the monodentate diaminochlorobenzene ligand, three acetate O atoms and two bridging hydroxide ligands. The tetrahedral coordination sphere consists of three acetate O atoms and the hydroxide ligand. The zinc ions are bridged by acetate and hydroxide ligands. The result is a laddered-chain structure parallel to [100] with ethanol solvent molecules occupying the space between the chains. The diamine ligand chlorine substitutent is disordered over two equally populated positions as a result of a crystallographically imposed inversion center between adjacent ligands. The ethanol solvent molecule exhibits disorder with the two components having refined occupancies of 0.696 (11) and 0.304 (11). O—H⋯O hydrogen bonds form between the hydroxide ligand and the ethanol solvent molecule. N—H⋯O and N—H⋯N hydrogen bonding between the uncoordinated amine group and the acetate ligands and the coordinated amine group are also observed. |
format | Online Article Text |
id | pubmed-4120637 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41206372014-08-26 Poly[[tris(μ(2)-acetato-κ(2) O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] Geiger, David K. Parsons, Dylan E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Zn(2)(CH(3)CO(2))(3)(OH)(C(6)H(7)ClN(2))]·C(2)H(5)OH}(n), has alternating octahedrally and tetrahedrally coordinated Zn(2+) ions. The octahedral coordination sphere is composed of one N atom of the monodentate diaminochlorobenzene ligand, three acetate O atoms and two bridging hydroxide ligands. The tetrahedral coordination sphere consists of three acetate O atoms and the hydroxide ligand. The zinc ions are bridged by acetate and hydroxide ligands. The result is a laddered-chain structure parallel to [100] with ethanol solvent molecules occupying the space between the chains. The diamine ligand chlorine substitutent is disordered over two equally populated positions as a result of a crystallographically imposed inversion center between adjacent ligands. The ethanol solvent molecule exhibits disorder with the two components having refined occupancies of 0.696 (11) and 0.304 (11). O—H⋯O hydrogen bonds form between the hydroxide ligand and the ethanol solvent molecule. N—H⋯O and N—H⋯N hydrogen bonding between the uncoordinated amine group and the acetate ligands and the coordinated amine group are also observed. International Union of Crystallography 2014-06-07 /pmc/articles/PMC4120637/ /pubmed/25161516 http://dx.doi.org/10.1107/S1600536814012641 Text en © Geiger and Parsons 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Geiger, David K. Parsons, Dylan E. Poly[[tris(μ(2)-acetato-κ(2) O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
title | Poly[[tris(μ(2)-acetato-κ(2)
O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
title_full | Poly[[tris(μ(2)-acetato-κ(2)
O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
title_fullStr | Poly[[tris(μ(2)-acetato-κ(2)
O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
title_full_unstemmed | Poly[[tris(μ(2)-acetato-κ(2)
O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
title_short | Poly[[tris(μ(2)-acetato-κ(2)
O:O′)(4-chlorobenzene-1,2-diamine-κN)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
title_sort | poly[[tris(μ(2)-acetato-κ(2)
o:o′)(4-chlorobenzene-1,2-diamine-κn)(μ(3)-hydroxido)dizinc] ethanol monosolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120637/ https://www.ncbi.nlm.nih.gov/pubmed/25161516 http://dx.doi.org/10.1107/S1600536814012641 |
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