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Stereodivergent Approach to the Avermectins Based on “Super Silyl” Directed Aldol Reactions
[Image: see text] A stereodivergent approach to the spiroketal fragment of the avermectins is described. The strategy utilizes a sequence of three aldol reactions directed by the tris(trimethylsilyl)silyl “super silyl” group. Central to this strategy is that each aldol reaction can be controlled to...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120983/ https://www.ncbi.nlm.nih.gov/pubmed/25025525 http://dx.doi.org/10.1021/ol501327g |