Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte

New solid polymer electrolytes (SPE) based on poly(ethylene oxide) (PEO) doped with lithium trifluoromethanesulfonate (LiCF(3)SO(3)), dibutyl phthalate (DBP) plasticizer, and zirconium oxide (ZrO(2)) nanoparticles were prepared by solution-casting technique. The conductivity was enhanced by addition...

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Detalles Bibliográficos
Autores principales: Yasin, Siti Mariah Mohd, Ibrahim, Suriani, Johan, Mohd Rafie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2014
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4124230/
https://www.ncbi.nlm.nih.gov/pubmed/25133244
http://dx.doi.org/10.1155/2014/547076
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author Yasin, Siti Mariah Mohd
Ibrahim, Suriani
Johan, Mohd Rafie
author_facet Yasin, Siti Mariah Mohd
Ibrahim, Suriani
Johan, Mohd Rafie
author_sort Yasin, Siti Mariah Mohd
collection PubMed
description New solid polymer electrolytes (SPE) based on poly(ethylene oxide) (PEO) doped with lithium trifluoromethanesulfonate (LiCF(3)SO(3)), dibutyl phthalate (DBP) plasticizer, and zirconium oxide (ZrO(2)) nanoparticles were prepared by solution-casting technique. The conductivity was enhanced by addition of dibutyl phthalate (DBP) plasticizer and ZrO(2) nanofiller with maximum conductivity (1.38 × 10(−4) Scm(−1)). The absorption edge and band gap values showed decreases upon addition of LiSO(3)CF(3), DBP, and ZrO(2) due to the formation of localized states in the SPE and the degree of disorder in the films increased.
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spelling pubmed-41242302014-08-17 Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte Yasin, Siti Mariah Mohd Ibrahim, Suriani Johan, Mohd Rafie ScientificWorldJournal Research Article New solid polymer electrolytes (SPE) based on poly(ethylene oxide) (PEO) doped with lithium trifluoromethanesulfonate (LiCF(3)SO(3)), dibutyl phthalate (DBP) plasticizer, and zirconium oxide (ZrO(2)) nanoparticles were prepared by solution-casting technique. The conductivity was enhanced by addition of dibutyl phthalate (DBP) plasticizer and ZrO(2) nanofiller with maximum conductivity (1.38 × 10(−4) Scm(−1)). The absorption edge and band gap values showed decreases upon addition of LiSO(3)CF(3), DBP, and ZrO(2) due to the formation of localized states in the SPE and the degree of disorder in the films increased. Hindawi Publishing Corporation 2014 2014-07-15 /pmc/articles/PMC4124230/ /pubmed/25133244 http://dx.doi.org/10.1155/2014/547076 Text en Copyright © 2014 Siti Mariah Mohd Yasin et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Yasin, Siti Mariah Mohd
Ibrahim, Suriani
Johan, Mohd Rafie
Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte
title Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte
title_full Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte
title_fullStr Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte
title_full_unstemmed Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte
title_short Effect of Zirconium Oxide Nanofiller and Dibutyl Phthalate Plasticizer on Ionic Conductivity and Optical Properties of Solid Polymer Electrolyte
title_sort effect of zirconium oxide nanofiller and dibutyl phthalate plasticizer on ionic conductivity and optical properties of solid polymer electrolyte
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4124230/
https://www.ncbi.nlm.nih.gov/pubmed/25133244
http://dx.doi.org/10.1155/2014/547076
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