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Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine

Hematite (α-Fe(2)O(3)) nanoparticles were synthesized by the solid transformation of ferrous hydroxide and ferrihydrite in hydrothermal condition. The as-prepared α-Fe(2)O(3) nanoparticles were characterized by UV-vis, PL, XRD, Raman, TEM, AFM, FESEM, and EDX analysis. The experimental results indic...

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Autores principales: Zangeneh Kamali, Khosro, Alagarsamy, Pandikumar, Huang, Nay Ming, Ong, Boon Hoong, Lim, Hong Ngee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4130303/
https://www.ncbi.nlm.nih.gov/pubmed/25136664
http://dx.doi.org/10.1155/2014/396135
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author Zangeneh Kamali, Khosro
Alagarsamy, Pandikumar
Huang, Nay Ming
Ong, Boon Hoong
Lim, Hong Ngee
author_facet Zangeneh Kamali, Khosro
Alagarsamy, Pandikumar
Huang, Nay Ming
Ong, Boon Hoong
Lim, Hong Ngee
author_sort Zangeneh Kamali, Khosro
collection PubMed
description Hematite (α-Fe(2)O(3)) nanoparticles were synthesized by the solid transformation of ferrous hydroxide and ferrihydrite in hydrothermal condition. The as-prepared α-Fe(2)O(3) nanoparticles were characterized by UV-vis, PL, XRD, Raman, TEM, AFM, FESEM, and EDX analysis. The experimental results indicated the formation of uniform hematite nanoparticles with an average size of 45 nm and perfect crystallinity. The electrochemical behavior of a GC/α-Fe(2)O(3) electrode was studied using CV and EIS techniques with an electrochemical probe, [Fe(CN)(6)](3−/4−) redox couple. The electrocatalytic activity was investigated toward DA oxidation in a phosphate buffer solution (pH 6.8) by varying different experimental parameters. The chronoamperometric study showed a linear response in the range of 0–2 μM with LoD of 1.6 μM for DA. Square wave voltammetry showed a linear response in the range of 0–35 μM with LoD of 236 nM for DA.
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spelling pubmed-41303032014-08-18 Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine Zangeneh Kamali, Khosro Alagarsamy, Pandikumar Huang, Nay Ming Ong, Boon Hoong Lim, Hong Ngee ScientificWorldJournal Research Article Hematite (α-Fe(2)O(3)) nanoparticles were synthesized by the solid transformation of ferrous hydroxide and ferrihydrite in hydrothermal condition. The as-prepared α-Fe(2)O(3) nanoparticles were characterized by UV-vis, PL, XRD, Raman, TEM, AFM, FESEM, and EDX analysis. The experimental results indicated the formation of uniform hematite nanoparticles with an average size of 45 nm and perfect crystallinity. The electrochemical behavior of a GC/α-Fe(2)O(3) electrode was studied using CV and EIS techniques with an electrochemical probe, [Fe(CN)(6)](3−/4−) redox couple. The electrocatalytic activity was investigated toward DA oxidation in a phosphate buffer solution (pH 6.8) by varying different experimental parameters. The chronoamperometric study showed a linear response in the range of 0–2 μM with LoD of 1.6 μM for DA. Square wave voltammetry showed a linear response in the range of 0–35 μM with LoD of 236 nM for DA. Hindawi Publishing Corporation 2014 2014-07-21 /pmc/articles/PMC4130303/ /pubmed/25136664 http://dx.doi.org/10.1155/2014/396135 Text en Copyright © 2014 Khosro Zangeneh Kamali et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Zangeneh Kamali, Khosro
Alagarsamy, Pandikumar
Huang, Nay Ming
Ong, Boon Hoong
Lim, Hong Ngee
Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine
title Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine
title_full Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine
title_fullStr Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine
title_full_unstemmed Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine
title_short Hematite Nanoparticles-Modified Electrode Based Electrochemical Sensing Platform for Dopamine
title_sort hematite nanoparticles-modified electrode based electrochemical sensing platform for dopamine
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4130303/
https://www.ncbi.nlm.nih.gov/pubmed/25136664
http://dx.doi.org/10.1155/2014/396135
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