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Activation of Alcohols with Carbon Dioxide: Intermolecular Allylation of Weakly Acidic Pronucleophiles
[Image: see text] The direct coupling of allyl alcohols with nitroalkanes, nitriles, and aldehydes using catalytic Pd(PPh(3))(4) has been accomplished via activation of C–OH bonds with CO(2). The in situ formation of carbonates from alcohols and CO(2) facilitates oxidative addition to Pd to form rea...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4136682/ https://www.ncbi.nlm.nih.gov/pubmed/25089846 http://dx.doi.org/10.1021/ol502023d |