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Reaction of an Iron(IV) Nitrido Complex with Cyclohexadienes: Cycloaddition and Hydrogen-Atom Abstraction

[Image: see text] The iron(IV) nitrido complex PhB(MesIm)(3)Fe≡N reacts with 1,3-cyclohexadiene to yield the iron(II) pyrrolide complex PhB(MesIm)(3)Fe(η(5)-C(4)H(4)N) in high yield. The mechanism of product formation is proposed to involve sequential [4 + 1] cycloaddition and retro Diels–Alder reac...

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Detalles Bibliográficos
Autores principales:	Lee, Wei-Tsung, Juarez, Ruth A., Scepaniak, Jeremiah J., Muñoz, Salvador B., Dickie, Diane A., Wang, Haobin, Smith, Jeremy M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4139179/ https://www.ncbi.nlm.nih.gov/pubmed/25068927 http://dx.doi.org/10.1021/ic5010006

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