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Mapping intermolecular bonding in C(60)

The formation of intermolecular bonds in C(60) has been investigated in detail at pressures below 2.2 GPa and up to 750 K. Fullerene samples were heated in a temperature gradient to obtain data on the formation of dimers and low-dimensional polymers along isobars. Intermolecular bonding was analyzed...

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Autor principal: Sundqvist, Bertil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4141248/
https://www.ncbi.nlm.nih.gov/pubmed/25145952
http://dx.doi.org/10.1038/srep06171
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author Sundqvist, Bertil
author_facet Sundqvist, Bertil
author_sort Sundqvist, Bertil
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description The formation of intermolecular bonds in C(60) has been investigated in detail at pressures below 2.2 GPa and up to 750 K. Fullerene samples were heated in a temperature gradient to obtain data on the formation of dimers and low-dimensional polymers along isobars. Intermolecular bonding was analyzed ex situ by Raman scattering, using both intramolecular modes and intermolecular stretching modes. Semi-quantitative reaction maps are given for the formation of dimers and chains. The activation energy for dimer formation decreases by 0.2 meV pm(−1) when intermolecular distances decrease and dimer formation is noticeably affected by the rotational state of molecules. Above 400–450 K larger oligomers are formed; below 1.4 GPa most of these are disordered, with small domains of linear chains, but above this the appearance of stretching modes indicates the existence of ordered one-dimensional polymers. At the highest pressures and temperatures two-dimensional polymers are also observed.
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spelling pubmed-41412482014-08-22 Mapping intermolecular bonding in C(60) Sundqvist, Bertil Sci Rep Article The formation of intermolecular bonds in C(60) has been investigated in detail at pressures below 2.2 GPa and up to 750 K. Fullerene samples were heated in a temperature gradient to obtain data on the formation of dimers and low-dimensional polymers along isobars. Intermolecular bonding was analyzed ex situ by Raman scattering, using both intramolecular modes and intermolecular stretching modes. Semi-quantitative reaction maps are given for the formation of dimers and chains. The activation energy for dimer formation decreases by 0.2 meV pm(−1) when intermolecular distances decrease and dimer formation is noticeably affected by the rotational state of molecules. Above 400–450 K larger oligomers are formed; below 1.4 GPa most of these are disordered, with small domains of linear chains, but above this the appearance of stretching modes indicates the existence of ordered one-dimensional polymers. At the highest pressures and temperatures two-dimensional polymers are also observed. Nature Publishing Group 2014-08-22 /pmc/articles/PMC4141248/ /pubmed/25145952 http://dx.doi.org/10.1038/srep06171 Text en Copyright © 2014, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-nd/4.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder in order to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/4.0/
spellingShingle Article
Sundqvist, Bertil
Mapping intermolecular bonding in C(60)
title Mapping intermolecular bonding in C(60)
title_full Mapping intermolecular bonding in C(60)
title_fullStr Mapping intermolecular bonding in C(60)
title_full_unstemmed Mapping intermolecular bonding in C(60)
title_short Mapping intermolecular bonding in C(60)
title_sort mapping intermolecular bonding in c(60)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4141248/
https://www.ncbi.nlm.nih.gov/pubmed/25145952
http://dx.doi.org/10.1038/srep06171
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