Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

[Image: see text] A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electroche...

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Autores principales: Johnson, Miles W., DiPasquale, Antonio G., Bergman, Robert G., Toste, F. Dean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4146325/
https://www.ncbi.nlm.nih.gov/pubmed/25180022
http://dx.doi.org/10.1021/om500663m
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author Johnson, Miles W.
DiPasquale, Antonio G.
Bergman, Robert G.
Toste, F. Dean
author_facet Johnson, Miles W.
DiPasquale, Antonio G.
Bergman, Robert G.
Toste, F. Dean
author_sort Johnson, Miles W.
collection PubMed
description [Image: see text] A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds.
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spelling pubmed-41463252015-08-12 Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors Johnson, Miles W. DiPasquale, Antonio G. Bergman, Robert G. Toste, F. Dean Organometallics [Image: see text] A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds. American Chemical Society 2014-08-12 2014-08-25 /pmc/articles/PMC4146325/ /pubmed/25180022 http://dx.doi.org/10.1021/om500663m Text en Copyright © 2014 American Chemical Society Terms of Use (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html)
spellingShingle Johnson, Miles W.
DiPasquale, Antonio G.
Bergman, Robert G.
Toste, F. Dean
Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
title Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
title_full Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
title_fullStr Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
title_full_unstemmed Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
title_short Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
title_sort synthesis of stable gold(iii) pincer complexes with anionic heteroatom donors
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4146325/
https://www.ncbi.nlm.nih.gov/pubmed/25180022
http://dx.doi.org/10.1021/om500663m
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