A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

Detalles Bibliográficos
Autores principales: Santoro, Orlando, Collado, Alba, Slawin, Alexandra M. Z., Nolan, Steven P., Cazin, Catherine S. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2013
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4155829/
https://www.ncbi.nlm.nih.gov/pubmed/24087835
http://dx.doi.org/10.1039/c3cc45488f
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author Santoro, Orlando
Collado, Alba
Slawin, Alexandra M. Z.
Nolan, Steven P.
Cazin, Catherine S. J.
author_facet Santoro, Orlando
Collado, Alba
Slawin, Alexandra M. Z.
Nolan, Steven P.
Cazin, Catherine S. J.
author_sort Santoro, Orlando
collection PubMed
description A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.
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spelling pubmed-41558292014-09-08 A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes Santoro, Orlando Collado, Alba Slawin, Alexandra M. Z. Nolan, Steven P. Cazin, Catherine S. J. Chem Commun (Camb) Chemistry A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air. Royal Society of Chemistry 2013-11-18 2013-10-01 /pmc/articles/PMC4155829/ /pubmed/24087835 http://dx.doi.org/10.1039/c3cc45488f Text en This journal is © The Royal Society of Chemistry 2013 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Santoro, Orlando
Collado, Alba
Slawin, Alexandra M. Z.
Nolan, Steven P.
Cazin, Catherine S. J.
A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
title A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
title_full A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
title_fullStr A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
title_full_unstemmed A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
title_short A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
title_sort general synthetic route to [cu(x)(nhc)] (nhc = n-heterocyclic carbene, x = cl, br, i) complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4155829/
https://www.ncbi.nlm.nih.gov/pubmed/24087835
http://dx.doi.org/10.1039/c3cc45488f
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