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Tandem Glycosyl Iodide Glycosylation and Regioselective Enzymatic Acylation Affords 6-O-Tetradecanoyl-α-d-cholesterylglycosides

[Image: see text] A generalized synthesis of α-d-cholesterylglycosides has been achieved using one-pot per-O-trimethylsilyl glycosyl iodide glycosidation. Both cholesteryl α-d-glucopyranoside (αCG) and cholesteryl α-d-galactopyranoside were prepared in high yield. These compounds were further esteri...

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Detalles Bibliográficos
Autores principales: Davis, Ryan A., Fettinger, James C., Gervay-Hague, Jacquelyn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156253/
https://www.ncbi.nlm.nih.gov/pubmed/25093454
http://dx.doi.org/10.1021/jo501371h

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