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The Cyanide Ligands of [FeFe] Hydrogenase: Pulse EPR Studies of (13)C and (15)N-Labeled H-Cluster
[Image: see text] The two cyanide ligands in the assembled cluster of [FeFe] hydrogenase originate from exogenous l-tyrosine. Using selectively labeled tyrosine substrates, the cyanides were isotopically labeled via a recently developed in vitro maturation procedure allowing advanced electron parama...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156861/ https://www.ncbi.nlm.nih.gov/pubmed/25133957 http://dx.doi.org/10.1021/ja507046w |