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The Cyanide Ligands of [FeFe] Hydrogenase: Pulse EPR Studies of (13)C and (15)N-Labeled H-Cluster

[Image: see text] The two cyanide ligands in the assembled cluster of [FeFe] hydrogenase originate from exogenous l-tyrosine. Using selectively labeled tyrosine substrates, the cyanides were isotopically labeled via a recently developed in vitro maturation procedure allowing advanced electron parama...

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Detalles Bibliográficos
Autores principales: Myers, William K., Stich, Troy A., Suess, Daniel L. M., Kuchenreuther, Jon M., Swartz, James R., Britt, R. David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156861/
https://www.ncbi.nlm.nih.gov/pubmed/25133957
http://dx.doi.org/10.1021/ja507046w