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Anion-Dependent Switch in C–X Reductive Elimination Diastereoselectivity
[Image: see text] Reaction of a complex Pt organometallic species with electrophilic halogen sources in the presence of X(–) ligands changes the mechanism of reductive elimination from a concerted reductive coupling type to an S(N)2 type reductive elimination. In the absence of the added X(–) ligand...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4157736/ https://www.ncbi.nlm.nih.gov/pubmed/25221379 http://dx.doi.org/10.1021/om5006929 |