3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile

The complete molecule of the title compound, C(26)H(20)N(2)O(2), is generated by a crystallographic twofold axis. The torsion angle between the terminal and central benzene rings is −32.5 (2)°. The torsion angle along the inner helical rim of the molecule is −18.8 (2)° with each other. The C⋯C dista...

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Detalles Bibliográficos
Autores principales: Sahasithiwat, Somboon, Sooksimuang, Thanasat, Kamtonwong, Siriporn, Parnchan, Waraporn, Kangkaew, Laongdao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158476/
https://www.ncbi.nlm.nih.gov/pubmed/25249890
http://dx.doi.org/10.1107/S1600536814014950
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author Sahasithiwat, Somboon
Sooksimuang, Thanasat
Kamtonwong, Siriporn
Parnchan, Waraporn
Kangkaew, Laongdao
author_facet Sahasithiwat, Somboon
Sooksimuang, Thanasat
Kamtonwong, Siriporn
Parnchan, Waraporn
Kangkaew, Laongdao
author_sort Sahasithiwat, Somboon
collection PubMed
description The complete molecule of the title compound, C(26)H(20)N(2)O(2), is generated by a crystallographic twofold axis. The torsion angle between the terminal and central benzene rings is −32.5 (2)°. The torsion angle along the inner helical rim of the molecule is −18.8 (2)° with each other. The C⋯C distance between the terminal rings is 3.016 (2) Å. In the crystal, weak C—H⋯N hydrogen bonds are observed.
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spelling pubmed-41584762014-09-23 3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile Sahasithiwat, Somboon Sooksimuang, Thanasat Kamtonwong, Siriporn Parnchan, Waraporn Kangkaew, Laongdao Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete molecule of the title compound, C(26)H(20)N(2)O(2), is generated by a crystallographic twofold axis. The torsion angle between the terminal and central benzene rings is −32.5 (2)°. The torsion angle along the inner helical rim of the molecule is −18.8 (2)° with each other. The C⋯C distance between the terminal rings is 3.016 (2) Å. In the crystal, weak C—H⋯N hydrogen bonds are observed. International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158476/ /pubmed/25249890 http://dx.doi.org/10.1107/S1600536814014950 Text en © Sahasithiwat et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sahasithiwat, Somboon
Sooksimuang, Thanasat
Kamtonwong, Siriporn
Parnchan, Waraporn
Kangkaew, Laongdao
3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
title 3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
title_full 3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
title_fullStr 3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
title_full_unstemmed 3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
title_short 3,12-Dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
title_sort 3,12-dimeth­oxy-5,6,9,10-tetra­hydro-[5]helicene-7,8-dicarbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158476/
https://www.ncbi.nlm.nih.gov/pubmed/25249890
http://dx.doi.org/10.1107/S1600536814014950
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