(3-Methyl­benzo­nitrile-1κN)-cis-tetra­kis(μ-N-phenyl­acetamidato)-1:2κ(4) N:O;1:2κ(4) O:N-dirhodium(II)(Rh—Rh)

The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(NCC(7)H(7))], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique Rh(II) atom ci...

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Detalles Bibliográficos
Autores principales: Eagle, Cassandra T., Quarshie, Fredricka, Cook, Kevin M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158479/
https://www.ncbi.nlm.nih.gov/pubmed/25249885
http://dx.doi.org/10.1107/S1600536814016031
Descripción
Sumario:The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(NCC(7)H(7))], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique Rh(II) atom cis to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)°. The axial nitrile ligand completes the distorted octa­hedral coordination sphere of one Rh(II) atom and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°; the N—C bond length is 1.154 (7) Å.

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