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(3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4) N:O;1:2κ(4) O:N-dirhodium(II)(Rh—Rh)
The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(NCC(7)H(7))], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique Rh(II) atom ci...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158479/ https://www.ncbi.nlm.nih.gov/pubmed/25249885 http://dx.doi.org/10.1107/S1600536814016031 |
| _version_ | 1782334053263867904 |
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| author | Eagle, Cassandra T. Quarshie, Fredricka Cook, Kevin M. |
| author_facet | Eagle, Cassandra T. Quarshie, Fredricka Cook, Kevin M. |
| author_sort | Eagle, Cassandra T. |
| collection | PubMed |
| description | The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(NCC(7)H(7))], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique Rh(II) atom cis to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)°. The axial nitrile ligand completes the distorted octahedral coordination sphere of one Rh(II) atom and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°; the N—C bond length is 1.154 (7) Å. |
| format | Online Article Text |
| id | pubmed-4158479 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41584792014-09-23 (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4) N:O;1:2κ(4) O:N-dirhodium(II)(Rh—Rh) Eagle, Cassandra T. Quarshie, Fredricka Cook, Kevin M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(NCC(7)H(7))], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique Rh(II) atom cis to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)°. The axial nitrile ligand completes the distorted octahedral coordination sphere of one Rh(II) atom and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°; the N—C bond length is 1.154 (7) Å. International Union of Crystallography 2014-07-23 /pmc/articles/PMC4158479/ /pubmed/25249885 http://dx.doi.org/10.1107/S1600536814016031 Text en © Eagle et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Eagle, Cassandra T. Quarshie, Fredricka Cook, Kevin M. (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4) N:O;1:2κ(4) O:N-dirhodium(II)(Rh—Rh) |
| title | (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4)
N:O;1:2κ(4)
O:N-dirhodium(II)(Rh—Rh) |
| title_full | (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4)
N:O;1:2κ(4)
O:N-dirhodium(II)(Rh—Rh) |
| title_fullStr | (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4)
N:O;1:2κ(4)
O:N-dirhodium(II)(Rh—Rh) |
| title_full_unstemmed | (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4)
N:O;1:2κ(4)
O:N-dirhodium(II)(Rh—Rh) |
| title_short | (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ(4)
N:O;1:2κ(4)
O:N-dirhodium(II)(Rh—Rh) |
| title_sort | (3-methylbenzonitrile-1κn)-cis-tetrakis(μ-n-phenylacetamidato)-1:2κ(4)
n:o;1:2κ(4)
o:n-dirhodium(ii)(rh—rh) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158479/ https://www.ncbi.nlm.nih.gov/pubmed/25249885 http://dx.doi.org/10.1107/S1600536814016031 |
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