Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile

The asymmetric unit of the title compound, C(14)H(22)N(2)O(2)Si(2), contains one half of the mol­ecule, which is completed by inversion symmetry. The cyclo­hexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs...

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Detalles Bibliográficos
Autores principales: Glöcklhofer, Florian, Fröhlich, Johannes, Stöger, Berthold, Weil, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158486/
https://www.ncbi.nlm.nih.gov/pubmed/25249859
http://dx.doi.org/10.1107/S1600536814014251
Descripción
Sumario:The asymmetric unit of the title compound, C(14)H(22)N(2)O(2)Si(2), contains one half of the mol­ecule, which is completed by inversion symmetry. The cyclo­hexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) Å]. The tetra­hedral angle between the sp (3)-C atom and the two neighbouring sp (2)-C atoms in the cyclo­hexa-2,5-diene ring is enlarged by about 3°.

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