Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile

The asymmetric unit of the title compound, C(14)H(22)N(2)O(2)Si(2), contains one half of the mol­ecule, which is completed by inversion symmetry. The cyclo­hexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs...

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Autores principales: Glöcklhofer, Florian, Fröhlich, Johannes, Stöger, Berthold, Weil, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158486/
https://www.ncbi.nlm.nih.gov/pubmed/25249859
http://dx.doi.org/10.1107/S1600536814014251
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author Glöcklhofer, Florian
Fröhlich, Johannes
Stöger, Berthold
Weil, Matthias
author_facet Glöcklhofer, Florian
Fröhlich, Johannes
Stöger, Berthold
Weil, Matthias
author_sort Glöcklhofer, Florian
collection PubMed
description The asymmetric unit of the title compound, C(14)H(22)N(2)O(2)Si(2), contains one half of the mol­ecule, which is completed by inversion symmetry. The cyclo­hexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) Å]. The tetra­hedral angle between the sp (3)-C atom and the two neighbouring sp (2)-C atoms in the cyclo­hexa-2,5-diene ring is enlarged by about 3°.
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spelling pubmed-41584862014-09-23 Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile Glöcklhofer, Florian Fröhlich, Johannes Stöger, Berthold Weil, Matthias Acta Crystallogr Sect E Struct Rep Online Research Communications The asymmetric unit of the title compound, C(14)H(22)N(2)O(2)Si(2), contains one half of the mol­ecule, which is completed by inversion symmetry. The cyclo­hexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) Å]. The tetra­hedral angle between the sp (3)-C atom and the two neighbouring sp (2)-C atoms in the cyclo­hexa-2,5-diene ring is enlarged by about 3°. International Union of Crystallography 2014-07-19 /pmc/articles/PMC4158486/ /pubmed/25249859 http://dx.doi.org/10.1107/S1600536814014251 Text en © Glöcklhofer et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Glöcklhofer, Florian
Fröhlich, Johannes
Stöger, Berthold
Weil, Matthias
Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
title Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
title_full Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
title_fullStr Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
title_full_unstemmed Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
title_short Crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
title_sort crystal structure of trans-1,4-bis­[(tri­methyl­sil­yl)­oxy]cyclo­hexa-2,5-diene-1,4-dicarbo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158486/
https://www.ncbi.nlm.nih.gov/pubmed/25249859
http://dx.doi.org/10.1107/S1600536814014251
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AT stogerberthold crystalstructureoftrans14bistrimethylsilyloxycyclohexa25diene14dicarbonitrile
AT weilmatthias crystalstructureoftrans14bistrimethylsilyloxycyclohexa25diene14dicarbonitrile

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