Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]

The title compound, [Li(2)(C(12)H(6)O(4))(H(2)O)(2)](n), crystallizes with one half of the molecular entities in the asymmetric unit. The second half is gererated by inversion symmetry. The crystal structure has a layered arrangement built from distorted edge-sharing LiO(3)(OH)(2) tetra­hedra parall...

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Autores principales: Fédèle, Lionel, Sauvage, Frédéric, Becuwe, Matthieu, Chotard, Jean-Noël
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158488/
https://www.ncbi.nlm.nih.gov/pubmed/25249875
http://dx.doi.org/10.1107/S1600536814013130
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author Fédèle, Lionel
Sauvage, Frédéric
Becuwe, Matthieu
Chotard, Jean-Noël
author_facet Fédèle, Lionel
Sauvage, Frédéric
Becuwe, Matthieu
Chotard, Jean-Noël
author_sort Fédèle, Lionel
collection PubMed
description The title compound, [Li(2)(C(12)H(6)O(4))(H(2)O)(2)](n), crystallizes with one half of the molecular entities in the asymmetric unit. The second half is gererated by inversion symmetry. The crystal structure has a layered arrangement built from distorted edge-sharing LiO(3)(OH)(2) tetra­hedra parallel to (100), with naphthalenedi­carboxyl­ate bridging the LiO(3)(OH)(2) layers along the [100] direction. Hydrogen bonding between the water molecule and adjacent carboxylate groups consolidates the packing.
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spelling pubmed-41584882014-09-23 Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)] Fédèle, Lionel Sauvage, Frédéric Becuwe, Matthieu Chotard, Jean-Noël Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Li(2)(C(12)H(6)O(4))(H(2)O)(2)](n), crystallizes with one half of the molecular entities in the asymmetric unit. The second half is gererated by inversion symmetry. The crystal structure has a layered arrangement built from distorted edge-sharing LiO(3)(OH)(2) tetra­hedra parallel to (100), with naphthalenedi­carboxyl­ate bridging the LiO(3)(OH)(2) layers along the [100] direction. Hydrogen bonding between the water molecule and adjacent carboxylate groups consolidates the packing. International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158488/ /pubmed/25249875 http://dx.doi.org/10.1107/S1600536814013130 Text en © Fédèle et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fédèle, Lionel
Sauvage, Frédéric
Becuwe, Matthieu
Chotard, Jean-Noël
Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
title Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
title_full Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
title_fullStr Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
title_full_unstemmed Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
title_short Poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
title_sort poly[μ(6)-(naphthalene-2,6-di­carboxyl­ato)-bis­(aqua­lithium)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158488/
https://www.ncbi.nlm.nih.gov/pubmed/25249875
http://dx.doi.org/10.1107/S1600536814013130
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