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(E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate
In the title chromone-tethered benzohydrazide derivative, C(21)H(20)N(2)O(7)·H(2)O, the atoms of the 4H-chromen-4-one segment are essentially coplanar (r.m.s. deviation = 0.0073 Å) with the largest deviation from the mean plane [0.012 (3) Å] being found for the benzene C atom. The dihedral angles be...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158489/ https://www.ncbi.nlm.nih.gov/pubmed/25249887 http://dx.doi.org/10.1107/S1600536814014937 |
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author | Ishikawa, Yoshinobu Watanabe, Kohzoh |
author_facet | Ishikawa, Yoshinobu Watanabe, Kohzoh |
author_sort | Ishikawa, Yoshinobu |
collection | PubMed |
description | In the title chromone-tethered benzohydrazide derivative, C(21)H(20)N(2)O(7)·H(2)O, the atoms of the 4H-chromen-4-one segment are essentially coplanar (r.m.s. deviation = 0.0073 Å) with the largest deviation from the mean plane [0.012 (3) Å] being found for the benzene C atom. The dihedral angles between the chromone segment and the hydrazide plane and between the chromone segment and the benzene ring of the trimethoxybenzene unit are 24.67 (9) and 41.28 (8) Å, respectively. The molecule is connected to the solvent water molecule by O—H⋯O hydrogen bonds and weak C—H⋯O interactions. Additional N—H⋯O interactions are observed and together they link the molecules into chains forming a two-dimensional network along (011). |
format | Online Article Text |
id | pubmed-4158489 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41584892014-09-23 (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate Ishikawa, Yoshinobu Watanabe, Kohzoh Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title chromone-tethered benzohydrazide derivative, C(21)H(20)N(2)O(7)·H(2)O, the atoms of the 4H-chromen-4-one segment are essentially coplanar (r.m.s. deviation = 0.0073 Å) with the largest deviation from the mean plane [0.012 (3) Å] being found for the benzene C atom. The dihedral angles between the chromone segment and the hydrazide plane and between the chromone segment and the benzene ring of the trimethoxybenzene unit are 24.67 (9) and 41.28 (8) Å, respectively. The molecule is connected to the solvent water molecule by O—H⋯O hydrogen bonds and weak C—H⋯O interactions. Additional N—H⋯O interactions are observed and together they link the molecules into chains forming a two-dimensional network along (011). International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158489/ /pubmed/25249887 http://dx.doi.org/10.1107/S1600536814014937 Text en © Ishikawa and Watanabe 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ishikawa, Yoshinobu Watanabe, Kohzoh (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title | (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_full | (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_fullStr | (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_full_unstemmed | (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_short | (E)-3,4,5-Trimethoxy-N′-[(6-methoxy-4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide monohydrate |
title_sort | (e)-3,4,5-trimethoxy-n′-[(6-methoxy-4-oxo-4h-chromen-3-yl)methylidene]benzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158489/ https://www.ncbi.nlm.nih.gov/pubmed/25249887 http://dx.doi.org/10.1107/S1600536814014937 |
work_keys_str_mv | AT ishikawayoshinobu e345trimethoxyn6methoxy4oxo4hchromen3ylmethylidenebenzohydrazidemonohydrate AT watanabekohzoh e345trimethoxyn6methoxy4oxo4hchromen3ylmethylidenebenzohydrazidemonohydrate |