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(E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate

In the title chromone-tethered benzohydrazide derivative, C(21)H(20)N(2)O(7)·H(2)O, the atoms of the 4H-chromen-4-one segment are essentially coplanar (r.m.s. deviation = 0.0073 Å) with the largest deviation from the mean plane [0.012 (3) Å] being found for the benzene C atom. The dihedral angles be...

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Detalles Bibliográficos
Autores principales: Ishikawa, Yoshinobu, Watanabe, Kohzoh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158489/
https://www.ncbi.nlm.nih.gov/pubmed/25249887
http://dx.doi.org/10.1107/S1600536814014937
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author Ishikawa, Yoshinobu
Watanabe, Kohzoh
author_facet Ishikawa, Yoshinobu
Watanabe, Kohzoh
author_sort Ishikawa, Yoshinobu
collection PubMed
description In the title chromone-tethered benzohydrazide derivative, C(21)H(20)N(2)O(7)·H(2)O, the atoms of the 4H-chromen-4-one segment are essentially coplanar (r.m.s. deviation = 0.0073 Å) with the largest deviation from the mean plane [0.012 (3) Å] being found for the benzene C atom. The dihedral angles between the chromone segment and the hydrazide plane and between the chromone segment and the benzene ring of the tri­meth­oxy­benzene unit are 24.67 (9) and 41.28 (8) Å, respectively. The mol­ecule is connected to the solvent water mol­ecule by O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions. Additional N—H⋯O inter­actions are observed and together they link the mol­ecules into chains forming a two-dimensional network along (011).
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spelling pubmed-41584892014-09-23 (E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate Ishikawa, Yoshinobu Watanabe, Kohzoh Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title chromone-tethered benzohydrazide derivative, C(21)H(20)N(2)O(7)·H(2)O, the atoms of the 4H-chromen-4-one segment are essentially coplanar (r.m.s. deviation = 0.0073 Å) with the largest deviation from the mean plane [0.012 (3) Å] being found for the benzene C atom. The dihedral angles between the chromone segment and the hydrazide plane and between the chromone segment and the benzene ring of the tri­meth­oxy­benzene unit are 24.67 (9) and 41.28 (8) Å, respectively. The mol­ecule is connected to the solvent water mol­ecule by O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions. Additional N—H⋯O inter­actions are observed and together they link the mol­ecules into chains forming a two-dimensional network along (011). International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158489/ /pubmed/25249887 http://dx.doi.org/10.1107/S1600536814014937 Text en © Ishikawa and Watanabe 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ishikawa, Yoshinobu
Watanabe, Kohzoh
(E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
title (E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
title_full (E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
title_fullStr (E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
title_full_unstemmed (E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
title_short (E)-3,4,5-Trimeth­oxy-N′-[(6-meth­oxy-4-oxo-4H-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
title_sort (e)-3,4,5-trimeth­oxy-n′-[(6-meth­oxy-4-oxo-4h-chromen-3-yl)methyl­idene]benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158489/
https://www.ncbi.nlm.nih.gov/pubmed/25249887
http://dx.doi.org/10.1107/S1600536814014937
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